磁化还原焙砂硫酸浸出探索

On Sulfuric Acid Leaching in Magnetized Reduction of Zinc from Calcines

针对锌浸出过程中铁大量进入溶液,由此带来的环境污染问题,本研究对锌还原焙砂的硫酸浸出过程进行系统研究.采用单因素条件试验法,详细考察硫酸初始酸度、液固比、温度和时间对还原焙砂浸出过程的影响,并在最佳工艺条件下进行综合扩大试验.结果表明,在硫酸初始酸度120 g/L、液固比7∶1、温度60℃、时间2 h的优化条件下,锌的浸出率达到了88.5%,铁的浸出率为1 0.6%.浸出液中铁几乎全部为二价铁离子,表明对锌焙砂的磁化还原过还原了.

In order to address the problem of iron flowing into solution in profusion in the process of zinc reduction which causes environmental pollution,this paper conducts a systematic research into the process of sulfuric acid leaching in reducing zinc from calcines. By adopting single-factor conditional testing,this paper thoroughly investigates various factors that affect the sulfuric acid leaching including the initial acidity,liquidsolid ratio,temperature and duration. The optimized testing shows that under the optimized condition with the initial acidity of 120 g/L,at liquid-solid ratio of 7∶1,at a temperature of 60 ℃ and in 2 hours the zinc leaching rate reaches 88.5%,the iron leaching rate 10.6% and the leached iron is almost totally ferrous iron. The result explains one step up to zinc calcine magnetized reduction of a reduction.