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还原气氛、助催化剂对SrTiO3光催化分解水制氢性能的影响

Effects of Reduced Atmosphere and Cocatalyst on Photocatalytic Activity of SrTiO_3 for Hydrogen Generation Through Water Splitting
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摘要 采用水热法制备了SrTiO3光催化材料,研究了在还原气氛下不同处理时间对SrTiO3光催化分解水制氢性能的影响;此外还研究了单一和复合助催化剂以及担载方法对光解水制氢性能的影响。结果表明:还原气氛中处理1h的样品,其制氢速率比未经处理的样品提高了近40%;担载单一助催化剂比复合助催化剂效果更好;光沉积Pt助催化剂样品具有最高的光催化活性。 Effects of treating time in reduced atmosphere,as well as single cocatalyst and multi-cocatalyst on the photocatalytic activity of SrTiO3 prepared by hydrothermal method for hydrogen generation through water splitting were investigated.Results indicated that the sample treated in reduced atmosphere for 1h showed the 40% enhanced photocatalytic activity for hydrogen evolution in comparison with the untreated sample.SrTiO3 loaded with single cocatalyst by photodeposition exhibited better performance than that of SrTiO3 loaded with multi-cocatlysts.Moreover,the sample loaded with Pt showed the highest activity.
出处 《材料导报》 EI CAS CSCD 北大核心 2015年第6期21-25,30,共6页 Materials Reports
基金 国家自然科学基金(21103041) 国家博士后基金(2011M500786) 河南大学科学与技术研究创新团队(2012IRTSTHN004)
关键词 SRTIO3 光催化 助催化剂 SrTiO3 photocatalysis cocatalyst
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参考文献33

  • 1Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972,238 : 37.
  • 2Kim T, Kim J, Choi K. Degradation mechanism and the toxicity assessment in TiO2 photocatalysis and photolysis of parathion[J]. Chemosphere, 2006,62(6): 926.
  • 3Varley J B, Janotti A, van de Walle C G. Mechanism of vi- sible-light photocatalysis in nitrogen-doped TiO2 [J]. Adv Mater, 2011,23(20) : 2343.
  • 4Banerjee S, Pillai S C, Falaras P. New insights into the mechanism of visible light photocatalysis[J]. J Phys Chem Lett,2014,5(15) :2543.
  • 5Schneider J, Matsuoka M, Takeuchi M. Understanding TiO2 photocatalysis: Mechanisms and materials[J]. Chem Rev, 2014,114(19) : 9919.
  • 6Kazunari D, et al. Mechanism of photocatalytic decomposi- tion of water into H2 and O2 over NiO/SrTiO3 [J]. J Catal, 1986,102(1) : 92.
  • 7Kato H, Asakura K, Kudo A. Highly efficient water split- ting into H2 and O2 over lanthanum-doped NaTaOa photo- catalysts with high crystallinity and surface nanostructure [J]. J Am Chem Soe,2003,125(10):3082.
  • 8Zou Z, Ye J, Sayama K. Direct splitting of water under vi- sible light irradiation with an oxide semiconductor photoca- talyst[J]. Nature, 2001,414(6864): 625.
  • 9Maeda K, Teramura K, Lu D. Photocatalyst releasing hy- drogen from water--Enhancing catalytic performance holds promise for hydrogen production by water splitting in sun- light[J]. Nature, 2006,440(7082) :295.
  • 10Chen X, Liu L, Yu P Y. Increasing solar abosorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals[J]. Science,2011,331(6018) :746.

二级参考文献16

  • 1Fujishima A, Rao T N, Truk D A. Titanium dioxide photocatalysis[J]. Photochem Photobiol C: Photochem Rev,2000 (1):1.
  • 2Murphy A B, Barnes P R F, Randeniya L K, et al. Efficiency of solar water splitting using semiconductor electrodes [J]. Int J Hydrogen Energy,2006,31: 1999.
  • 3Xie Y B, Yuan C W. Characterization and photocatalysis of Eu^3+-TiO2 sol in the hydrosol reaction system[J]. Mater Res Bull,2004,39(4-5) :533.
  • 4Singh A P, Kumari S, Shrivastavb R, et al. Iron doped nanostruetured TiO2 for photoelectrochemical generation of hydrogen[J]. Int J Hydrogen Energy, 2008,33 : 5363.
  • 5Tang H, Prasad K, Sanjines R, et al. Electricaland optical properties of TiO2 anatase thin films[J]. J Appl Phys, 1994, 75(4):2042.
  • 6Lindgren T, Mwabora J M, Avendano E, et al. Photoelectrochemieal and optical properties of nitrogen doped titanium dioxide films prepared by reactive de magnetron sputtering [J]. J Phys Chem B,2003,107:5709.
  • 7Tong T, Zhang J, Tian B, et al. Preparation of Fe^3+ doped TiO2 catalysts by controlled hydrolysis of titanium alkoxide and study on their photocatalytic activity for methyl orange degradation[J]. J Hazard Mater,2008,155 : 572.
  • 8Wang X H, Li J G, Kamiyama H, et al. Wavelength-sensitive photocatalytic degradation of methyl orange in aqueous suspensionover iron (Ⅲ)-doped TiO2 nanopowders under UV and visible light irradiation[J]. J Phys Chem B, 2006, 110:6804.
  • 9Wang C Y, Bottcher C, Bahnemann DW, et al. A comparative study of nanometer sized Fe(Ⅲ)-doped TiO2 photocatalysts: Synthesis, characterization and activity[J]. J Mater Chem, 2003,13 : 2322.
  • 10Choi W, Termin A, Hoffmann M R. The role of metal ion dopants in quantum-sized TiO2 : Correlation between photoreactivity and charge carrier recombination dynamics[J]. J Phys Chem, 1994,98 : 13669.

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