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钛配合物/氧化石墨烯复合储氢材料的制备及其性能研究

Synthesis, Activation, Characterization and Properties of Titanium Complexes/Graphene Ox ide Composite Materials
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摘要 文章提出了一种"盆栽"型的钛配合物/氧化石墨烯复合储氢材料模型,以层状石墨为原料制备出高氧化程度的氧化石墨烯,探讨用氧化石墨烯来担载过氟钛酸铵进行储氢性能的可行性。氟钛酸铵/氧化石墨烯复合材料在333 K、453 K和573 K活化1 h后,在77 K,1.2 Mpa时储氢量分别为1.4 wt%、1.2 wt%和2.6 wt%。 The paper presents a way of a "pot" type titanium complexes/graphene oxide composite hydrogen storage material model. The layered graphite as material was prepared graphene oxide, the oxidation degree of the obtained high based on the structure of graphene oxide, the graphene oxide to explore the use of transition metal titanium for supporting the feasibility of hydrogen. Ammonium titanium composites, respectively 333 K, 453 K and 573 K activated 1 h, at 77 k, 1.2 Mpa, the hydrogen storage capacity was 1.4 wt%, 1.2 wt% and 2.6 wt%.
出处 《广东化工》 CAS 2015年第8期40-41,39,共3页 Guangdong Chemical Industry
基金 晶态碳基能量转换与储存材料的合成策略及其电极过程本质(No.21031001)
关键词 氧化石墨烯 钛配合物 储氢 graphene oxide titanium complexes hydrogen storage
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参考文献4

  • 1Ghosh S, Bao W, Calizo I, et al. Superior thermal conductivity of single-layergraphene[J]. NanoLetters, 2008, 8(3): 902-907.
  • 2Hamaed A, Trudeau M, Antonelli D, et al. H2 storage materials (22 KJ/mol) using organ metallic Ti fragments as sigma-H2 binding sites[J]. Journal of the American Chemical Society, 2008, 130(22): 6992-6999.
  • 3Sreeprasad TS, Maliyekkal SM, Lisha KP, et al. Reduced graphene oxide-metal/metal oxide composites: Facile synthesis and application in water purification[J]. J HazardMater, 2011, 186(1): 921-931.
  • 4Czajka MS, Robert A. Preparation of graphene and inclusion in composites with poly(styrene-b-butadiene-b-styrene)[J] . Science and Engineering ofCompositeMaterials, 2015, 22: 7-16.

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