基于最小吉布斯自由能的疏水表面接触角模型

M odel of contact angle of hydrophobic surface based on minimum Gibbs free energy

在光滑表面Young氏方程和粗糙表面Cassie-Baxter模型的基础上,建立了二维情况下基于最小吉布斯自由能的接触角预测模型,并且对预测模型进行了修正,考虑斜壁对气-液接触线的影响。利用接触角预测模型及其修正研究微结构材料和尺寸参数对接触角大小的影响,从而指导疏水性微结构设计。研究结果表明,疏水性基底相对于亲水性基底加工出的微结构有更大的接触角提升趋势。增大微结构间隙宽度,减小凸台宽度,减小微结构斜壁角度,有利于接触角的提升。

Based on the function of Young used for smooth surface and the model of Cassie-Baxter used for rough sur- face, the prediction model for contact angle of hydrophobic surface based on minimum Gibbs free energy was proposed. The model for contact angle prediction was then modified by considering the influence of skew walls on the contact line between gas-liquid. The effects of hydrophobic surface material properties and geometric parameters on contact angle were analyzed based on the modified model. The results showed that, under the same condition of machined micro-surface, the contract angle on the hydrophobic surface root was larger than that on the hydrophilic one. Besides, for the Cassie-Baxter model, the larger radio between the width of groove and the width of convex was, the larger contract angle was.