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生物催化硫醚底物的不对称氧化反应研究进展 被引量：1

Research Progress on Asymmetric Oxidation of Sulfides with Biocatalysts
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摘要 综述了生物催化硫醚底物的不对称氧化反应的研究进展,重点介绍了微生物菌株整细胞、纯酶和基因工程菌等催化剂在硫醚底物的不对称氧化反应中的应用。参考文献32篇。 Research progress on the asymmetric oxidation of sulfides with biocatalysts were reviewd with 32 references. The biocatalysts,such as whole cells of microorganisms,purified enzymes and engineering strains which have been widely used in the asymmetric oxidation of sulfides,were discussed in detail.
作者 卓俊睿 陈永正
机构地区 遵义医学院药学院
出处 《合成化学》 CAS CSCD 2015年第5期456-460,共5页 Chinese Journal of Synthetic Chemistry
基金 国家自然科学基金资助项目(21262051) 贵州省科技厅项目(QKHGZ-2011-7017)
关键词 生物催化 硫醚 整细胞 基因过程菌 不对称氧化 biocatalysis sulfide whole cell engineering strain asymmetric oxidation
分类号 O622.7 [理学—有机化学]
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参考文献32

  • 1Wojaczytiska E, WojaczytiskiJ. Enantioselective synthesis of sulfoxides , 2000 - 2009[J]. Chern Rev, 2010,110:4303 -4356.
  • 2Holland H L, Brown F M, Larsen B G. Preparation of (R) -sulfoxides by biotransformation using Helmituhosporium species NRRL 4671[J] . Tetrahedron: Asymmetry, 1994,5: 1129 -1l30.
  • 3Holland H L, Brown F M, Larsen B G. Biotransformation of organic sulfides. Part 6. Formation of chiral para-substituted benzyl methyl sulfoxides by Helmituhosporium. species NRRL 4671[J]. Tetrahedron: Asymmetry, 1995,6: 1561 -1567.
  • 4Holland H L, Bommann MJ, Lakshmaiah G. Biotransformation of organic sulfides. Part 9. Formation of ( S) -para substituted phenyl methyl sulfoxides by biotransformation using Helmintlwsporium species NRRL 4671[J].J Mol Catal B:Enzym,1996,1:97 -102.
  • 5Holland H L, Allen LJ, Chemishenko MJ, et al. Side chain oxidation of aromatic compounds by fungi. 7. A rationale for sulfoxidation, benzylic hydroxylation, and olefin oxidation by Mortierella isabeUina[J].J Mol Catal B:Enzym,1997,3 :311 -324.
  • 6Holland H L, Brown F M. Biocatalytic and chemical preparation of all four diastereomers of methionine sulfoxide[J]. TetrahedronAsymmetry, 1998,9 :535 -538.
  • 7Herbert L, Holland H L, Brown F M, et al. Biotransformation of sulfides by Rhodocoeccus erythropolis[J] .J Mol Catal B: Enzym,2003,22:219 -223.
  • 8FrenchJ B, Holland G, Holland H L, et al. A comparative molecular field analysis of the biotransformation of sulfides by Rhodococcus erythropolis[J] .J Mol Catal B:Enzym,2004,31:87 -96.
  • 9Kelly DR, Knowles CJ, MahdiJ G, et al. The enantioselective oxidation of sulfides to sulfoxides with Acinetobacter sp. NCIMB 9871, Pseudomonas sp. NCIMB 9872, Xatuhobacter autotrophicus DSM 431 ( NCIMB 10811) and the Black Yeast NV - 2[J]. Tetrahedron : Asymmetry, 1996 ,7 : 365 - 368.
  • 10Pinedo-Rivilla C, AleuJ, Cpllado I G. Enantioslective oxidation of organic sulfides by the filamentous fungi Botrytis cinerea, Eutypa lata and Trichoderma viride[J] .J Mol Catal B: Enzym ,2007 ,49: 18 - 23.

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合成化学
2015年 第5期

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