有机硅试剂参与过渡金属催化的C-H官能团化反应形成C-C键的研究进展

Advance of Organosilane in Transition-Metal-Catalyzed C-H Functionalization for C-C Bond Formation

作为一类重要的有机金属试剂,有机硅试剂在有机合成化学的C—C键形成中得到了广泛应用.综述了近年来有机硅试剂参与的过渡金属催化下C—H官能团化反应形成C—C键的研究进展,重点介绍了Pd催化下C—H官能团化的Hiyama偶联反应.

As a kind of important organometallic reagents, organosilanes have been widely applied for C--C bond formation in organic synthesis. In this paper, recent development of trans-metal-catalyzed C--H functionalizations for C--C bond for- mation involving organosilanes is reviewed, in which Pd-catalyzed Hiyama coupling reactions is described as highlighted.