摘要
The boroxine-linked organic aluminum compound LAl[OB（3-C4H3O）]2（μ-O） was accomplished by reacting LAl H2 {L =（Z）-4-[（2,6-diisopropylphenyl）amino]pent-3-en-2-ylidene-2,6-diisopropylaniline} with furan-3-ylboronic acid in good yield.The title compound belongs to the orthorhombic system,space group Pnma with a = 10.9774（15）,b = 19.369（3）,c = 17.362（3） A,V = 3691.5（9） A^3,C37H47 Al B2N2O5,Mr = 648.37,Z = 4,Dc = 1.167 Mg/m^3,μ（Mo Kα） = 0.097 mm^–1,F（000） = 1384,S = 1.000,the final R = 0.0589 and w R = 0.1445 for 9138 observed reflections（I 〉 2σ（I）） and R = 0.0683 and w R = 0.1517 for all data.This compound is an unique example of a spiro-centered aluminum atom,showing the inorganic Al O3B2 ring fused to the organic C3N2 part.It was characterized by 1H NMR,IR,elemental analysis,and single-crystal X-ray structural analysis.Furthermore,the compound was studied by TG analysis as well as DSC.
The boroxine-linked organic aluminum compound LAl[OB（3-C4H3O）]2（μ-O） was accomplished by reacting LAl H2 {L =（Z）-4-[（2,6-diisopropylphenyl）amino]pent-3-en-2-ylidene-2,6-diisopropylaniline} with furan-3-ylboronic acid in good yield.The title compound belongs to the orthorhombic system,space group Pnma with a = 10.9774（15）,b = 19.369（3）,c = 17.362（3） A,V = 3691.5（9） A^3,C37H47 Al B2N2O5,Mr = 648.37,Z = 4,Dc = 1.167 Mg/m^3,μ（Mo Kα） = 0.097 mm^–1,F（000） = 1384,S = 1.000,the final R = 0.0589 and w R = 0.1445 for 9138 observed reflections（I 〉 2σ（I）） and R = 0.0683 and w R = 0.1517 for all data.This compound is an unique example of a spiro-centered aluminum atom,showing the inorganic Al O3B2 ring fused to the organic C3N2 part.It was characterized by 1H NMR,IR,elemental analysis,and single-crystal X-ray structural analysis.Furthermore,the compound was studied by TG analysis as well as DSC.
基金
supported by the National Natural Science Foundation of China(No.21001016)
the Beijing Natural Science Foundation(No.2132044)
Beijing High School Youth Talent Project(YETP1191)
