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Electrochemical impedance spectroscopy study on the corrosion of the weld zone of 3Cr steel welded joints in CO_2 environments 被引量:8

Electrochemical impedance spectroscopy study on the corrosion of the weld zone of 3Cr steel welded joints in CO_2 environments
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摘要 The welded joints of 3Cr pipeline steel were fabricated with commercial welding wire using the gas tungsten arc welding(GTAW) technique. Potentiodynamic polarization curves, linear polarization resistance(LPR), electrochemical impedance spectroscopy(EIS), scanning electron microscopy(SEM), and energy-dispersive spectrometry(EDS) were used to investigate the corrosion resistance and the growth of a corrosion film on the weld zone(WZ). The changes in electrochemical characteristics of the film were obtained through fitting of the EIS data. The results showed that the average corrosion rate of the WZ in CO2 environments first increased, then fluctuated, and finally decreased gradually. The formation of the film on the WZ was divided into three stages: dynamic adsorption, incomplete-coverage layer formation, and integral layer formation. The welded joints of 3Cr pipeline steel were fabricated with commercial welding wire using the gas tungsten arc welding (GTAW) technique. Potentiodynamic polarization curves, linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS), scan- ning electron microscopy (SEM), and energy-dispersive spectrometry (EDS) were used to investigate the corrosion resistance and the growth of a corrosion film on the weld zone (WZ). The changes in electrochemical characteristics of the film were obtained through fitting of the EIS data. The results showed that the average corrosion rate of the WZ in CO2 environments first increased, then fluctuated, and finally de- creased gradually. The formation of the film on the WZ was divided into three stages: dynamic adsorption, incomplete-coverage layer forma- tion, and integral layer formation.
出处 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2015年第5期500-508,共9页 矿物冶金与材料学报(英文版)
基金 financial support from the Natural Science Foundation of China (No. 51371034)
关键词 电化学阻抗谱 焊接区 腐蚀膜 管线钢 环境 CO2 扫描电子显微镜 钨极氩弧焊 petroleum pipelines steel corrosion welded joints carbon dioxide electrochemical impedance spectroscopy
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