期刊文献+

第三代RHT系列催化剂在高氮低硫和高铁钙类型渣油加氢装置上的工业应用 被引量:12

APPLICATION OF THE THIRD GENERATION RHT SERIES CATALYSTS FOR HYDROTREATING VR WITH HIGH N,LOW S AND HIGH Fe AND Ca CONTENT
下载PDF
导出
摘要 中国石化长岭分公司1.7Mt/a加氢装置加工的渣油属于典型的高氮低硫和高铁钙含量类型,加氢反应难度大,床层压降大。第二周期采用中国石化石油化工科学研究院(简称石科院)开发的第三代RHT系列催化剂,在优化催化剂级配的基础上,与第一周期使用的石科院开发的第二代RHT系列催化剂相比,运行周期、加工量和掺渣量等指标提升明显,残炭降低效果好。 A 1.7 Mt/a residue hydrotreating unit of SINOPEC Changling Company, processed the feedstock with high S and low N, and high Fe and Ca content. The feed is difficult to be hydrotreated and easy to cause pressure drop. The 2^nd cycle of the unit adopted the 3^rd generation RHT series catalysts developed by SINOPEC Research Institute of Petroleum Processing with an optimized catalyst grading. The commercial results demonstrate that the cycle life, processing capacity and mixing slag quantity increase obviously by the use of the 3ra generation RHT catalysts, compared with the second generation of RHT series catalyst, meanwhile the carbon residue conversion effect is better.
作者 陈大跃 涂彬
出处 《石油炼制与化工》 CAS CSCD 北大核心 2015年第6期46-51,共6页 Petroleum Processing and Petrochemicals
关键词 渣油加氢 催化剂 残炭 residue hydrotreating catalyst sulfur nitrogen iron calcium carbon residue
  • 相关文献

参考文献6

二级参考文献40

  • 1胡大为,杨清河,刘滨,牛传峰.上流式渣油加氢催化剂的开发及工业放大[J].石油炼制与化工,2006,37(1):1-3. 被引量:15
  • 2张佩甫.原油中金属杂质的危害及脱除方法[J].石油化工腐蚀与防护,1996,13(1):9-11. 被引量:22
  • 3刘久长,张广林.石油和石油产物中非烃化合物[M].北京:中国石化出版社,1991:347-348.
  • 4Maity S, Ancheyta J, Rana M. Support effects on hydropro- cessing of Maya heavy crude[J]. Energy & Fuels, 2005,19 (2) :343-347.
  • 5Toulhoat H, Szymanski R, Plumail J. Interrelations between initial pore structure, morphology and distribution of accumu- lated deposits,and lifetimes of hydrodemetaltisation catalysts [J]. Catal Today,1990,7(4) :531-568.
  • 6Aneheyta J,Rana M, Furimsky E. Hydroprocessing of heavy petroleum feeds: Tutorial[J]. Catal Today, 2005,109 : 3-15.
  • 7Tamm P, Harnsberg H, Bridge A. Effects of feed metals on catalyst aging in hydroprocessing residuum [J ]. Ind Eng Chem Process Des Develop, 1981,20(2) :262- 273.
  • 8Kobayashi S, Kushiyama S, Aizawa R, et al. Kinetic study on the hydrotreating of heavy oil. 2. Effect of catalyst pore size [J]. Ind Eng Chem Res,1987,26(11) :2245-2250.
  • 9Callejas M, Martinez M, Fierro J, et al. Structural and mor- phological study of metal deposition on an aged hydrotreating catalyst[J]. Applied Catal : A General, 2001,220 : 93-104.
  • 10Chen H, Massoth F. Hydrodemetallisation of vanadium and nickel porphyrins over sulfided cobalt-molybdenum/alumina catalyst[J]. Ind Eng Chem Res, 1988,27(9) : 1629-1639.

共引文献23

同被引文献82

引证文献12

二级引证文献43

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部