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Modulating the metal/organic interface via Cu TCNQ decorated layer toward high performance bottom-contact single-crystal transistors

Modulating the metal/organic interface via Cu TCNQ decorated layer toward high performance bottom-contact single-crystal transistors
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摘要 The organic single-crystal field-effect transistors using anthracene derivative, H-Ant as an active layer with source/drain electrodes decorated by metal charge transfer salt(Cu TCNQ) were fabricated. We demonstrated that this bottom-contact structure displayed an obvious improvement in the electrical characteristics relative to their pristine copper and top-contact gold electrode counterparts. This observation could be ascribed to the lower contact resistance resulting from the energetic match between electrodes and semiconductor. The organic single-crystal field-effect transistors using anthracene derivative, H-Ant as an active layer with source/drain elec- trodes decorated by metal charge transfer salt (CuTCNQ) were fabricated. We demonstrated that this bottom-contact structure displayed an obvious improvement in the electrical characteristics relative to their pristine copper and top-contact gold elec- trode counterparts. This observation could be ascribed to the lower contact resistance resulting from the energetic match be- tween electrodes and semiconductor.
出处 《Science China Chemistry》 SCIE EI CAS CSCD 2015年第6期1027-1031,共5页 中国科学(化学英文版)
基金 supported by the National Natural Science Foundation of China(20721061,51033006,51003107,91027043) the China-Denmark Co-project,TRR61(NSFC-DFG Transregio Project) the National Basic Research Program of China(2011CB808400,2011CB932300,2009CB930400)and Chinese Academy of Sciences
关键词 metal charge transfer salt anthracene derivative organic single-crystal field-effect transistors 金属/有机界面 CuTCNQ 场效应晶体管 单晶 底部 装饰层 性能 电荷转移盐
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