摘要
The trisilanol isobutyl polyhedral oligomeric silsesquioxane（POSS） was fabricated into liquid-like nano- particle organic hybrid materials（NOHMs） with ）,-（2,3-epoxypropoxy）propytrimethoxysilane as corona and polyethe- ramine M2070 as canopy, and the product was called liquid-like POSS NOHM. The liquid-like POSS NOHM has a low viscosity at room temperature without any solvent and the mass fraction of trisilanol isobutyl POSS was 23.38%. The liquid-like POSS NOHM shows great CO2 capturing property with a capacity of 2.108 mmol/g（PCO2=6 MPa）. The physical adsorption increased obviously with the pressure going up and it may make a difference between liquid-like POSS NOHMs and traditional monoethamolamine（MEA） based CO2 absorbent. The recycle property was also studied. The NOHM behaved as fresh product even after 10 cycles.
The trisilanol isobutyl polyhedral oligomeric silsesquioxane（POSS） was fabricated into liquid-like nano- particle organic hybrid materials（NOHMs） with ）,-（2,3-epoxypropoxy）propytrimethoxysilane as corona and polyethe- ramine M2070 as canopy, and the product was called liquid-like POSS NOHM. The liquid-like POSS NOHM has a low viscosity at room temperature without any solvent and the mass fraction of trisilanol isobutyl POSS was 23.38%. The liquid-like POSS NOHM shows great CO2 capturing property with a capacity of 2.108 mmol/g（PCO2=6 MPa）. The physical adsorption increased obviously with the pressure going up and it may make a difference between liquid-like POSS NOHMs and traditional monoethamolamine（MEA） based CO2 absorbent. The recycle property was also studied. The NOHM behaved as fresh product even after 10 cycles.
基金
the National Natural Science Foundation of China（Nos.51373137, 51373136） and the Key Project of the Graduation Design Project of Northwestern Polytechnical University of China（No.20141101）.
