轴向取代可溶性硅酞菁衍生物制备与性能测试

Preparation and investigation of axially substituted soluble silicon phthalocyanine complexes

制备了一系列烷氧基轴向取代硅酞菁,改善了硅酞菁在有机溶剂中的溶解性;轴向取代的金属酞菁配合物相对于周边取代的金属酞菁配合物更易于制备。对这3个化合物进行了系统的结构表征(核磁氢谱、红外光谱、液相色谱-质谱联用),证实了这3个化合物是目标产物,并在不同溶剂中对它们进行紫外光谱、荧光光谱测试。

In this paper, a series of alkoxy phthalocyanine with axially substituted silicon were prepared and synthesized, and their solubility in common organic solvent was improved. Compared with the preparation of peripherally substituted metal phthalocyanine complexes ,that of these axially substituted metal phthalocyanine complexes was easier. Their chemical structures were characterized by 1H NMR, IR,LC mass. Furthermore, their UV spectra and fluorescence spectra in different solvents were investigated.