三(戊烷氧基)苯-一(1,4-二噻英)四氮杂卟啉的合成

The Synthesis of Tri(pentyloxy) phenyl-(1,4-dithiin) porphyrazines

前驱体2,3-二氰基-1,4-二噻英由顺式-1,2-二氰基-1,2-乙二硫钠盐与1,2-二溴乙烷反应生成,前驱体4-戊烷氧基邻苯二腈由正戊醇与4-硝基邻苯二腈反应得到,然后用"镁模板法"合成不对称的三(戊烷氧基)苯-一(1,4-二噻英)四氮杂卟啉,产率为43%。并对其自由配体进行了紫外光谱和Maldi-TOF MS表征。

s： The precursor 2,3-dithiolate-1,4-dithiin was synthesized from disodium salt of dithiomaleonitrile and 1, 2-dibromoethane, and the other precursor 4 -pentyloxy -phthalic nitrile was synthesized from n -amyl alcohol and 4 -nitrophthalonitrile. The tri（ pentyloxy） phenyl-（1,4 -dithiin） porphyrazines was synthesized from these precursors by magnesium template reaction method and characterized by UV-Vis and Maldi-TOF MS.