摘要
The catalytic oxidation of nitrogen oxide( NO) from waste gas was investigated using advanced oxidation process based on sulfate radicals. The manganese oxide immobilized on graphene oxide( GO) can activate peroxymonosulfate( PMS) for the oxidation of NO in waste gas. The Mn3O4 / GO catalyst system was characterized via X-ray diffraction( XRD), Fourier transform infrared spectrocopy( FT-IR), Raman spectroscopy, X-ray photoelectron spectroscopy( XPS), energy dispersive X-ray spectroscopy( EDS),and scanning electron microscope( SEM).The results showed that Mn3O4 was distributed on GO. The Mn3O4 /GO catalyst system exhibited efficient activity for NO oxidation when the Mn3O4 /GO catalyst had an optimum Mn3O4 loading. In addition,the best catalytic oxidation could be achieved within 60 min with 0. 25 mmol /L Mn3 O4 /GO catalyst, and2 mmol /L PMS dosage at 25 ℃. The catalysts also exhibited stable performance after several rounds of regeneration. Therefore,the results may have significant technical implication for utilizing Mn3O4 /PMS to oxidize NO for offgas treatment.
The catalytic oxidation of nitrogen oxide（ NO） from waste gas was investigated using advanced oxidation process based on sulfate radicals. The manganese oxide immobilized on graphene oxide（ GO） can activate peroxymonosulfate（ PMS） for the oxidation of NO in waste gas. The Mn3O4 / GO catalyst system was characterized via X-ray diffraction（ XRD）, Fourier transform infrared spectrocopy（ FT-IR）, Raman spectroscopy, X-ray photoelectron spectroscopy（ XPS）, energy dispersive X-ray spectroscopy（ EDS）,and scanning electron microscope（ SEM）.The results showed that Mn3O4 was distributed on GO. The Mn3O4 /GO catalyst system exhibited efficient activity for NO oxidation when the Mn3O4 /GO catalyst had an optimum Mn3O4 loading. In addition,the best catalytic oxidation could be achieved within 60 min with 0. 25 mmol /L Mn3 O4 /GO catalyst, and2 mmol /L PMS dosage at 25 ℃. The catalysts also exhibited stable performance after several rounds of regeneration. Therefore,the results may have significant technical implication for utilizing Mn3O4 /PMS to oxidize NO for offgas treatment.
基金
Education Innovation Project of Shanghai,China(No.12ZZ069)
Natural Science Foundation of Shanghai,China(No.11ZR1400400)
Doctoral Fund of Ministry of Education of China(No.20130075110006)
Modification Fiber Materials Project of the National Key Laboratory of China(No.LK1203)
