摘要
9位官能化的2,7-二溴芴衍生物（1~7）是以9H-芴为原料,先后经溴化、氧化或烷基化得到,反应条件温和,分离简便,产率高（80%~99%）,特别是2,7-二溴芴氧化成2,7-二溴芴酮（1）,在绿色环保条件下即可完成,符合绿色化学理念及原子经济性,化合物1~7的结构都经过核磁共振1H、13C谱确认.
A convenient, isolated easy, mild procedure was developed for the preparation of functionalized 2,7-dibromofluorene derivatives （ 1 -7） by trearment of 9H-fluorene with Br2 firstly, then alkylation or oxidation with high yield （80 % - 99 % ）, oxidized 2,7-dibromofluorene to compound 1 under especially green conditions in line with the concept of green chemistry and atom economy, and the products was charactered by ^1H,^13C NMR.
出处
《赣南师范学院学报》
2015年第3期53-56,共4页
Journal of Gannan Teachers' College(Social Science(2))
基金
江西省自然科学基金(20114BAB203001)
教育厅科技基金(GJJ11724)
