茂锆配合物的合成与应用研究进展

The research progress in synthesis and application of zirconocene complexes

茂锆配合物作为一类应用广泛的有机合成催化剂被深入地研究并取得了丰硕的成果.本文作者对近年来茂锆配合物的合成、性质及应用方面的研究进展进行了综述,重点概述了茂锆配合物的结构及其最新合成方法;此外,还介绍了茂金属配合物在催化烯烃聚合反应以及有机合成中的应用,并对茂锆配合物的应用研究前景进行了展望.

As a kind of widely used organic synthesis catalyst, zirconocene complexes was in- depth studied. In this paper, the research progress in the synthesis, properties and applications of zirconocene complexes were reviewed. The structure and their newest synthetic method of zirconocene complexes were summaried. Additionally, the application of catalyst in olefin poly- merization reaction and organic synthesis were discussed. At the same time, the application re- search prospect of zirconocene complexes were expected.