摘要
A detailed investigation of a thermodynamic process in a structured packing distillation column is of great impor- tance in prediction of process efficiency. In order to keep the simplicity of an equilibrium stage model and the accu- racy of a non-equilibrium stage model, a hybrid model is developed to predict the structured packing column in cryogenic air separation. A general solution process for the equilibrium stage model is developed to solve the set of equations of the hybrid model, in which a separation efficiency function is introduced to obtain the resulting tri-diagonal matrix and its solution by the Thomas algorithm. As an example, the algorithm is applied to analyze an upper column of a cryogenic air separation plant with the capacity of 17000 m3·h-1. Rigorous simulations are conducted using Aspen RATEFRAC module to validate the approach. The temperature and composition distributions are in a good agreement with the two methods. The effects of inlet/outlet position and flow rate on the temperature and composition distributions in the column are analyzed. The results demonstrate that the hybrid model and the solution algorithms are effective in analvzin~ the distillation process for a a cryogenic structured packing column.
A detailed investigation of a thermodynamic process in a structured packing distillation column is of great importance in prediction of process efficiency.In order to keep the simplicity of an equilibrium stage model and the accuracy of a non-equilibrium stage model,a hybrid model is developed to predict the structured packing column in cryogenic air separation.A general solution process for the equilibrium stage model is developed to solve the set of equations of the hybrid model,in which a separation efficiency function is introduced to obtain the resulting tri-diagonal matrix and its solution by the Thomas algorithm.As an example,the algorithm is applied to analyze an upper column of a cryogenic air separation plant with the capacity of 17000 m^3·h^(-1).Rigorous simulations are conducted using Aspen RATEFRAC module to validate the approach.The temperature and composition distributions are in a good agreement with the two methods.The effects of inlet/outlet position and flow rate on the temperature and composition distributions in the column are analyzed.The results demonstrate that the hybrid model and the solution algorithms are effective in analyzing the distillation process for a cryogenic structured packing column.
基金
Supported by the Major State Basic Research Development Program of China(2011CB706501)
the National Natural Science Foundation of China(51276157)
