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无机固体化合物中常见的氢键类型、结构和强度 被引量:4

Types,Structures and Strengths of Hydrogen Bonds in Inorganic Solids
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摘要 分析了无机固体化合物中常见的氢键给体和受体、常见的氢键类型、常见的氢键结构以及影响氢键强度的各种因素。氢键的强度与氢键给体和受体有关,也和氢键的结构排列有关。此外,氢键给体X-H中X原子和受体原子Y的配位以及其他结构效应(如协同、合作、反合作或竞争效应)及晶体的堆积都会影响氢键的强度。 The common hydrogen-bond donors and acceptors,hydrogen-bond types,structures and strengths of hydrogen bonds in inorganic solids were discussed.The strengths of hydrogen bonds depend on both the hydrogen-bond donors and acceptors and the structural arrangement of the hydrogen bonds.In addition,the coordination of the donor and acceptor atoms X and Y and other structural effects(as synergetic,cooperative,anti-cooperative or competitive effect)and crystal packing phenomena have to be considered.
出处 《化学教育》 CAS 北大核心 2015年第10期12-18,共7页 Chinese Journal of Chemical Education
基金 南京师范大学无机化学教学团队(181220001538)
关键词 氢键 无机固体化合物 给体 受体 协同效应 竞争效应 hydrogen bond inorganic solid donor acceptor synergetic effect competitiveeffect
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