摘要
分析了无机固体化合物中常见的氢键给体和受体、常见的氢键类型、常见的氢键结构以及影响氢键强度的各种因素。氢键的强度与氢键给体和受体有关,也和氢键的结构排列有关。此外,氢键给体X-H中X原子和受体原子Y的配位以及其他结构效应(如协同、合作、反合作或竞争效应)及晶体的堆积都会影响氢键的强度。
The common hydrogen-bond donors and acceptors,hydrogen-bond types,structures and strengths of hydrogen bonds in inorganic solids were discussed.The strengths of hydrogen bonds depend on both the hydrogen-bond donors and acceptors and the structural arrangement of the hydrogen bonds.In addition,the coordination of the donor and acceptor atoms X and Y and other structural effects(as synergetic,cooperative,anti-cooperative or competitive effect)and crystal packing phenomena have to be considered.
出处
《化学教育》
CAS
北大核心
2015年第10期12-18,共7页
Chinese Journal of Chemical Education
基金
南京师范大学无机化学教学团队(181220001538)
关键词
氢键
无机固体化合物
给体
受体
协同效应
竞争效应
hydrogen bond
inorganic solid
donor
acceptor
synergetic effect
competitiveeffect