期刊文献+

添加TiC和Cr_3C_2对超细WC-8Co硬质合金微观结构和性能的影响 被引量:13

Effect of TiC and Cr_3C_2 Addition on Microstructures and Properties of Ultrafine WC-8Co Cemented Carbides
下载PDF
导出
摘要 在WC-8Co硬质合金中添加不同含量的TiC和Cr3C2,用X射线衍射、扫描电镜分析了添加微量的TiC与Cr3C2对WC-8Co硬质合金微观结构的影响,通过硬度和断裂韧性测试,研究了TiC与Cr3C2含量对材料力学性能的影响。实验结果表明:添加适量TiC和Cr3C2能使超细硬质合金中WC晶粒尺寸细小且晶粒分布更为均匀,微观结构得以优化,从而改善硬质合金力学性能。此外,添加微量TiC能起到细化WC晶粒的作用,提高合金硬度,而添加Cr3C2能够显著抑制硬质合金中硬脆Co6W6C相的形成,从而改善合金的断裂韧性。 With adding various contents of TiC and Cr3C2 into the WC-8Co ultrafine cemented carbides,the effects of the TiC or Cr3C2 addition on the microstructure and mechanical properties of the cemented carbides were investigated by X-ray diffraction( XRD),scanning electron microscopy( SEM),hardness and fracture toughness test,respectively. The results show that alloys with homogeneous microstructure and ultrafine grain structure forms,and excellent properties are obtained when the optimal proportion of TiC or Cr3C2 is added. Moreover,Minor TiC addition refines the WC grains and increases the hardness of the alloys,while the addition of Cr3C2 decreases the volume fraction of Co6W6C phase in ultrafine WC-8Co alloys and thus increases the fracture toughness of alloys.
出处 《人工晶体学报》 EI CAS CSCD 北大核心 2015年第5期1336-1341,共6页 Journal of Synthetic Crystals
基金 广东省引进领军人才专项资金 广东省高等学校科技创新重点项目
关键词 WC-8Co TIC CR3C2 微观结构 力学性能 WC-8Co TiC Cr3C2 microstructure mechanical property
  • 相关文献

参考文献14

  • 1Breval E, Cheng J P, Agrawal D K, et al. Comparison Between Microwave and Conventional Sintering of WC/Co Composites [J]. MaterialsScience and Engineering : A ,2005,391 ( 1-2 ) :285-295.
  • 2赵志伟,郑红娟,刘颖,邹文俊,左宏森,关春龙.放电等离子烧结制备超细WC基硬质合金[J].材料热处理学报,2010,31(8):40-45. 被引量:9
  • 3Sha L. Study on Rare-earth Doped Cemented Carbides in China [ J 1. International Journal of Refractory Metals and Hard Materials,2009,27 (3) : 528-534.
  • 4Shen T T, Xiao D H, Ou X Q, et al. Effects of LaB6 Addition on the Microstructure and Mechanical Properties of Uhrafine Grained WC-10Co Alloys [ J ]. Journal of Alloys and Compounds,2011 ,$09 (4) : 1236-1243.
  • 5王冲,邵刚勤,段兴龙.纳米复合WC-Co粉末成型与烧结研究进展[J].硅酸盐通报,2005,24(1):97-100. 被引量:3
  • 6Sun L, Jia C, Cao R, et al. Effects of Cr3 C2 Additions on the Densification, Grain Growth and Properties of Ultrafine WC-11 Co Composites by Spark Plasma Sintering [ J ]. International Journal of Refractory Metals and Hard Materials, 2008,26 ( 4 ) : 357-361.
  • 7Lee K H, Cha S I, Kim B K, et al. Effect of WC/TiC Grain Size Ratio on Microstructure and Mechanical Properties of WC-TiC-Co Cemented Carbides[ J~. International Journal of Refractory Metals and Hard Materials ,2006,24( 1 ) : 109-14.
  • 8Vander M, Sacks N. Effect of TaC and TiC on the Friction and Dry Sliding Wear of WC-6wt% Co Cemented Carbides Against Steel Counted'aces [ J ]. International Journal of Refractory Metals and Hard Materials,2013,41:94-102.
  • 9Zhou W, Xiong J, Wan W, et al. The Effect of NbC on Mechanical Properties and Fracture Behavior of WC-10Co Cemented Carbides[ J~. International Journal of Refractory Metals and Hard Materials,2014,50:72-78.
  • 10肖代红,贺跃辉,罗伟红,宋旼.Effect of VC and NbC additions on microstructure and properties of ultrafine WC-10Co cemented carbides[J].中国有色金属学会会刊:英文版,2009,19(6):1520-1525. 被引量:15

二级参考文献28

  • 1王洪涛,王旭,余永宁.纳米WC/Co硬质合金粉末烧结早期的晶粒长大研究[J].稀有金属与硬质合金,2005,33(1):18-21. 被引量:17
  • 2张立,陈述,刘刚,杨贵彬,黄泽兰,黄伯云,张传福.高性能超细、纳米硬质合金及其制备过程中的关键技术问题[J].材料导报,2005,19(11):4-7. 被引量:21
  • 3HUANG S G, LI L, Vanmeensel K, et al. VC, Cr3C2 and NbC doped WC-Co cemented carbides prepared by pulsed electric current sintering[ J]. International Journal of Refractory Metals and Hard Materials, 2007, 25 (5 - 6 ) : 417 - 422.
  • 4ZHANG F M, SHEN J, SUN J F. The effect of phosphorus additions on densification, grain growth and properties of nanocrystalline WC-Co composites[ J ]. Journal of Alloys and Compounds, 2004, 385 ( 1 - 2) : 96 - 103.
  • 5Rodiger K, Dreyer K, Gerdes T, et al. Microwave sintering of hardmetals[ J ]. International Journal of Refractory Metals and Hard Materials, 1998, 16 (4 -6) : 409 -416.
  • 6SUN J F, ZHANG F M, SHEN J. Characterizations of ball-milled nanocrystalline WC-Co composite powders and subsequently rapid hot pressing sintered eermets [ J ]. Materials Letters, 2003, 57 (21 ) : 3140 - 3148.
  • 7CHA S I, HONG S H, Kim B K. Spark plasma sintering behavior of nanocrystalline WC-10Co cemented carbide powders[ J]. Materials Science and Engineering A, 2003, 351 (1 -2): 31 -38.
  • 8Omori M. Sintering, consolidation, reaction and crystal growth by the spark plasma system (SPS) [ J]. Materials Science and Engineering A, 2000, 287(2) : 183 - 188.
  • 9FANG Z, Eason J W. Study of nanost ruetured WC-Co composites[ A]. Proc 13^th Int. Plansee Seminar[ C] //Reutte: Plansee A G, 1993, 3: 625.
  • 10Shubert W D, Bock A, Lux B. General aspects and limits of conventional ultrafine WC powder manufacture and hard metal production [ J]. International Journal of Refractory Metals and Hard Materials, 1995, 13 (3) : 281 - 296.

共引文献24

同被引文献117

引证文献13

二级引证文献25

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部