氮配位过渡金属配合物在硅氢加成反应中的应用研究

The Application on Nitrogen-Coordinating Transition Metal Complexes on Hydrosilylation

氮配位过渡金属配合物在近十几年来得到迅速的发展。通过设计不同的含氮配体与不同过渡金属进行配位形成的氮配位过渡金属配合物,在硅氢加成反应中有很大应用研究价值。本文综述了氮配位铑、铁、铼、钴、锌等过渡金属配合物在酮或者烯烃的硅氢加成反应中的新进展。二唑啉及二氢吡咯等含氮配体的优化设计必将大大促进含氮铁、铼、钴配合物在酮或者亚胺的硅氢加成反应中的应用。

The study of nitrogen-coordinating transition metal complexes has been a significant development in the recent decades. Designing different excellent nitrogen ligands coordinated w ith various transition metal complexes,w hich its of great value in hydrosilylation reaction. In this paper,the latest progress of the application in nitrogen-coordinating transition metal（ Rh,Fe,Re,Co,Zn and so on） complexes to ketone hydrosilylation or alkene hydrosilylation is review ed. The design of optimized bisoxazolines or dihydropyrrolo nitrogen-containing ligands w ill greatly facilitate the successful development of nitrogen-containing iron,rhenium,cobalt complexes in the hydrosilylation of ketone or imine.