摘要
先用马来酸酐(MA)和二乙醇胺(DEA)合成了单体M,后与丙烯醇(AA)、烯丙基聚氧乙烯醚(B-400)用过硫酸胺(APS)作引发剂,在水溶液中通过自由基聚合合成新型高分子水泥助磨剂,确定了最佳单体摩尔比:M:AA:B-400=1.0:1.2:0.5,引发剂用量为单体总质量的4.0%。将该助磨剂应用于水泥粉磨试验,并与空白对比:45μm筛余量降低34.3%;3~32μm细颗粒的含量提高了18.2%;3d,28d的抗压强度分别提高了15.7%,13.7%。
The small monomer M was synthesized with maleic anhydr ide (MA) and die thano 1 amine (DEA). The Mand allyl alcoho 1 (AA)were then added into allyl polyeth enoxy e the r (B-400) to produce polymer cement grinding a idby aqueous solut ion polymerization, under the initiating effect of ammonium peroxydi sul fate, the optimal molar ratio of polyme r cement gr inding aid was M:A A:B-400=1:1. 2:0. 5, amount of initiator 4. 0%. The resul t s of the cement grinding aids test compared wi th black were as follows: sieved particles of 45μm reduced 34. 3%; the grains size of 3-32μm increased 18. 2%; 3d,28dcompres s ive streng th of cement pastes were increa sed by 15. 7%and 13. 7%.