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Franck-Condon Factors and Band Origins for MgH in the A2П-X2∑+ System

Franck-Condon Factors and Band Origins for MgH in the A2П-X2∑+ System
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摘要 We measure the dispersed spectrum of the A2H-X2E+ system of MgH using laser abla- tion/laser induced Fluorescence method and obtain the Frank-Condon factors and related transition frequencies of the A2H(v'=0)-X2∑+(v"=0,1) system by analyzing the experimental spectrum. Also, we calculate the Franck-Condon factors and transition frequencies of the A2H-X2∑+ system of MgH. A comparison of our theoretical calculation and experimental results with other reported theoretical results was carried out as well.
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2015年第3期253-256,I0001,共5页 化学物理学报(英文)
基金 This work was supported by the National Nature Science Foundation of China (No.61205198, No.11105052) and the Fundamental Research Fhnds for the Central Universities. The authors thank Chao Hang from State Key Laboratory of Precision Spectroscopy, East China Normal University and Timothy Steimles from Chemistry and Biochemistry Department, Arizona State University for the discussion.
关键词 Franck-Condon factors Energy curve Vibrational frequencies Dispersed fluorescence 光谱分析系统 因子和 法兰 激光诱导荧光法 起源 过渡频率 激光消融 跃迁频率
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