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紫根水葫芦干根粉吸附剂表面特征及吸砷(As)特性 被引量:1

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摘要 指出了紫根水葫芦干根粉对As(Ⅲ)和As(Ⅴ)吸附能力都明显优于传统生物吸附剂,其比表面积1.75-1.8m^2/g,仅为活性炭比表面积的1/55,在砷含量为1mg/L的溶液中对砷的吸附率为89%。在20-60℃范围内,干根粉对As(Ⅲ)的饱和吸附量为1.14-1.92mg/g,而As(Ⅴ)为1.86-2.51mg/g,对As(Ⅴ)的吸附能力高于As(Ⅲ),且温度越高吸附能力越大。溶液中干根粉吸附As(Ⅲ)的最佳pH值为7.5,As(Ⅴ)为3.0。研究发现:紫根水葫芦根粉吸附砷是通过其表面的活性基团起作用的,其中-OH、-NH2和-COOH通过电子共享或传递的方式与As(Ⅲ)或As(Ⅴ)形成化学键,从而将其束缚于根粉上;结构不同于As(Ⅲ)和As(Ⅴ)的粒子存在几乎不会对吸附作用产生影响。
出处 《绿色科技》 2015年第7期210-213,共4页 Journal of Green Science and Technology
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