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Synthesis, Crystal Structure, Luminescent Property and DNA-Binding of a Cadmium Complex with 2,4-Bis-oxyacetate-benzoic Acid 被引量：1

Synthesis, Crystal Structure, Luminescent Property and DNA-Binding of a Cadmium Complex with 2,4-Bis-oxyacetate-benzoic Acid
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摘要 A complex [Cd2Na2(BOABA)2(H2O)8]·H2O(1) was synthesized by using 2,4-bisoxyacetate-benzoic acid(H3BOABA) and Cd(OH)2. It was characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. Complex 1 shows a two-dimensional 3-connected rigid plane. The interactions between the ligand and its complex with DNA were studied by Et Br fluorescence probe. Photoluminescent studies indicate that the complex may be excellent candidates for potential photoactive materials. A complex [Cd2Na2（BOABA）2（H2O）8]·H2O（1） was synthesized by using 2,4-bisoxyacetate-benzoic acid（H3BOABA） and Cd（OH）2. It was characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. Complex 1 shows a two-dimensional 3-connected rigid plane. The interactions between the ligand and its complex with DNA were studied by Et Br fluorescence probe. Photoluminescent studies indicate that the complex may be excellent candidates for potential photoactive materials.
作者 郭航鸣 沈伟 陈小菊 赵国良
机构地区 Jinhua Radio and Television University College of Chemistry and Life Science Xingzhi College
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2015年第7期1080-1086,共7页 结构化学（英文）
基金 supported by the Natural Science Project of Zhejiang Province(LY12B01003)
关键词 镉配合物 晶体结构 发光性能 合成 DNA 单晶X射线衍射 元素分析 红外光谱 Cd complex 2 4-bis-oxyacetate-benzoic acid crystal structure DNA-binding photoluminescence
分类号 O621.2 [理学—有机化学]
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Chinese Journal of Structural Chemistry
2015年 第7期

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