摘要
The process of order to recover aluminum investigated. The CS was activating coal spoil （CS） in as a high value product was first characterized by X-ray fluorescence （XRF）, X-ray diffraction （XRD） and thermo- gravimetric analysis-differential scanning calorimetry （TGA-DSC） in order to determine the chemical and mineral compositions of the CS. Then a mechanothermal activation method was adopted to increase the aluminum activity in the coal spoil. Over 95% of the aluminum in the CS could be extracted using this activation method. The mechanothermal activation process promoted the destruc- tion of kaolinite structures and hindered the formation of amorphous γ-Al2O3. This resulted in a high aluminum leaching activity in the mechanothermally activated CS.
The process of order to recover aluminum investigated. The CS was activating coal spoil （CS） in as a high value product was first characterized by X-ray fluorescence （XRF）, X-ray diffraction （XRD） and thermo- gravimetric analysis-differential scanning calorimetry （TGA-DSC） in order to determine the chemical and mineral compositions of the CS. Then a mechanothermal activation method was adopted to increase the aluminum activity in the coal spoil. Over 95% of the aluminum in the CS could be extracted using this activation method. The mechanothermal activation process promoted the destruc- tion of kaolinite structures and hindered the formation of amorphous γ-Al2O3. This resulted in a high aluminum leaching activity in the mechanothermally activated CS.
基金
This work was financially supported by the National High Technology Research and Development Program of China （Grant No. 2011AA06A102）, the National Natural Science Foundation ofChina （Grant No. 21306053）, the Key Project of Scientific Research Innovation of Shanghai Municipal Education Commission （Grant No. 14ZZ063）, and the Fundamental Research Fund for the Central Universities （WB1213008）.
