摘要
利用XRD研究了化学镀Ni-P合金镀层经不同温度热处理后的结构变化。结果表明,镀态Ni-P呈非晶态;350℃时镀层由非晶态向晶态转化;热处理温度为400℃时,析出Ni3P稳定相。镀态及热处理条件下的阻垢和耐蚀性实验结果表明,随着热处理温度的升高,CaCO3中Ca的原子分数先降低后升高,300℃热处理降低了镀层的内应力及氢脆,使镀层的组织更加致密,镀层的阻垢和耐蚀性得到改善。
The effect of heat treatment temperature on the microstructural evolution of electroless plated Ni-P coatings was investigated using X-ray diffraction (XRD) analysis. The results showed that the as plated electroless Ni-P coating is amorphous. After heat treatment at 350 ℃, Ni-P coat- ings turn into crystalline state, while Ni3P phase appeared at 400 ℃. With the increasing heat treat- ment temperature, the Ca^2 + atomic percentage of the formed fouling scales reduced firstly at 300℃, and then increased at 350 and 400℃. After heat treatment at 300℃, the internal stress and hydrogen embrittleness of the coating was eliminated, thereby, the anti-fouling performance and corrosion resistance of the coating was enhanced.
出处
《腐蚀科学与防护技术》
CAS
CSCD
北大核心
2015年第4期349-352,共4页
Corrosion Science and Protection Technology
基金
辽宁省教育厅2012年科学研究一般项目(L2012127)
2013年度辽宁省普通本科高等学校实验教学示范中心建设项目
辽宁石油化工大学2014年教育教学改革研究项目(2014523060002和2014523080025)资助
关键词
化学镀
热处理
阻垢性
耐蚀性
electroless, heat treatment, anti-fouling, corrosion resistance