基于氢键的超分子自组装研究进展

Research Progress of Hydrogen Bonding Self-assemble in Supramolecule

综述了氢键在寡聚酰胺体系、喹啉衍生物体系、吡啶酰胺体系、氨基苯甲酰胺体系、菲咯啉酰胺体系、芳香酰肼体系、吡嗪咪唑酰胺体系、尿基衍生物体系的自组装过程中所起的作用及氢键在分子自组装中的发展现状.氢键具有可逆性,基于氢键的超分子自组装体系具有组装的多样性和广泛性等特点,据此可以预测氢键对自组装体结构和性质的影响,为设计和合成出结构稳定、性能优异、可以自由调控的材料提供理论基础.

The article reviews the role and recent progress of hydrogen bonding in different types of self-assembly of oligomeric aromatic amide,ologomeric quinoline derivative,picolinamide,anthranilic acid amide oligomer,phenanthroline polymer,hydrazide,pyrazine-imidazole acetamide,urea derivative and so on. The self-assembly based on hydrogen bonds possess the diversity and universality due to the reversibility of hydrogen bonds. Therefore,the influence of the structure and property of hydrogen bonds on self-assembly can be predicted. It can provide the theory basis for designing and synthesizing of the materials with structure stability,excellent property and free controlling.