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Copper-catalyzed arenes amination with saccharins 被引量:1

Copper-catalyzed arenes amination with saccharins
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摘要 A novel copper-catalyzed direct C–N formation reaction of simple arenes with cheap and pharmacological saccharin derivatives under relatively mild conditions was developed with arenes as limiting reagents.This work provided a new method for oxidative coupling of aromatic C(sp2)–H bonds and N–H bonds. A novel copper-catalyzed direct C-N formation reaction of simple arenes with cheap and pharmacological saccharin deriva- tives under relatively mild conditions was developed with arenes as limiting reagents. This work provided a new method for oxidative coupling of aromatic C(sp2)-H bonds and N-H bonds.
出处 《Science China Chemistry》 SCIE EI CAS CSCD 2015年第8期1354-1358,共5页 中国科学(化学英文版)
基金 financially supported by the National Natural Science Foundation of China(21172033,21372041,21302017)
关键词 aromatic amines C-N bond formation ARENES saccharins arenes as limiting reagents 糖精衍生物 铜催化 芳烃 胺化 C-N SP2 试剂 反应
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