摘要
The visible and near-UV emission spectroscopy of methane （CH4） induced by a femtosecond intense laser field （800 nm, 40 fs, 1014 W/cm2） is studied. By measuring the decay profiles of the neutral fragment product CH （A2△→X2П）, two reaction pathways, i.e., the electron-ion recombination through e- ＋ CH＋ and the direct disintegration of CH＋ are found to be responsible for populating the electronic excited states of the neutral fragment product CH, which gives rise to the photoemissions. Our results provide complementary information on previous understanding of the strong-field-induced photoemission mechanism of CH4 through neutral dissociation of superexcited states.
The visible and near-UV emission spectroscopy of methane （CH4） induced by a femtosecond intense laser field （800 nm, 40 fs, 1014 W/cm2） is studied. By measuring the decay profiles of the neutral fragment product CH （A2△→X2П）, two reaction pathways, i.e., the electron-ion recombination through e- ＋ CH＋ and the direct disintegration of CH＋ are found to be responsible for populating the electronic excited states of the neutral fragment product CH, which gives rise to the photoemissions. Our results provide complementary information on previous understanding of the strong-field-induced photoemission mechanism of CH4 through neutral dissociation of superexcited states.
基金
partially supported by the National Natural Science Foundation of China (61427816 and 61235003)
the National Basic Research Program of China (2014CB921300)
the Research Fund for the Doctoral Program of Higher Education of China
the Open Fund of the State Key Laboratory of High Field Laser Physics (SIOM),Canada Research Chairs, NSERC, Femtotech and FQRNT
