有机碳酸酯合成工艺研究进展

Progress in the Synthetic of Organic Carbonate

有机碳酸酯是一类重要的化学品,常被用于化学反应的溶剂和一元醇或二元醇的醇羟基保护基团。文章对有机碳酸酯的各种方法进行了综述,介绍了有机碳酸酯的性质和应用,着重介绍了它的合成方法,包括光气法、酯交换法、氧化羰基化法、尿素法、二氧化碳和醇直接合成法、一氧化碳气相催化偶联合成法和电化学法。

Organic carbonate is a kind of important chemical; they have widespread application as solvents for a variety of processes and as efficient protecting groups for alcohols and diols. In the paper, the synthesis methods of organic carbonate were reviewed, the paper introduces the properties and applications of organic carbonate, its synthesis method are introduced, including the phosgene, ester exchange, and oxidative carbonylation method, urea method in the direct synthesis method, carbon monoxide, carbon dioxide and alcohol vapor phase catalytic coupling joint method and electrochemical method.