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Characterization and chemical surface texturization of bulk ZnTe crystals grown by temperature gradient solution growth 被引量:1

Characterization and chemical surface texturization of bulk ZnTe crystals grown by temperature gradient solution growth
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摘要 Using tellurium as a solvent, we grew ZnTe ingots of 30 mm in diameter and 70 mm in length by a temperature gradient solution growth method. Hall tests conducted at 300 K indicated that the as-grown ZnTe exhibits p-type conductivity, with a carrier concentration of approximately 10^14cm^-3, a mobility of approximately 300 cm^2·V·s^-1, and a resistivity of approximately 10^2 Ω·cm. A simple and effective method was proposed for chemical surface texturization of ZnTe using an HF:H2O2:H2O etchant. Textures with the sizes of approximately 1μm were produced on {100}, {110}, and { 111}zn surfaces after etching. The etchant is also very promising in crystal characterization because of its strong anisotropic character and Te-phase selectivity. Using tellurium as a solvent, we grew ZnTe ingots of 30 mm in diameter and 70 mm in length by a temperature gradient solution growth method. Hall tests conducted at 300 K indicated that the as-grown ZnTe exhibits p-type conductivity, with a carrier concentration of approximately 10^14cm^-3, a mobility of approximately 300 cm^2·V·s^-1, and a resistivity of approximately 10^2 Ω·cm. A simple and effective method was proposed for chemical surface texturization of ZnTe using an HF:H2O2:H2O etchant. Textures with the sizes of approximately 1μm were produced on {100}, {110}, and { 111}zn surfaces after etching. The etchant is also very promising in crystal characterization because of its strong anisotropic character and Te-phase selectivity.
出处 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2015年第7期755-761,共7页 矿物冶金与材料学报(英文版)
基金 financially supported by the National Basic Research Program of China (No. 2011CB610406) the National Natural Science Foundation of China (No. 51372205) supported by the 111 Project of China (No. B08040) the Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 20116102120014) the Northwestern Polytechnical University Foundation for Fundamental Research the Research Fund of the State Key Laboratory of Solidification Processing (NWPU)
关键词 semiconductor materials crystal growth electrical properties surfaces ETCHING microstructure semiconductor materials crystal growth electrical properties surfaces etching microstructure
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