摘要
In this article, 12-acryloyloxystearic acid was synthesized, which was then used to prepare the magnesium 12-acryloyloxy stearate detergent. Reaction conditions for synthesizing 12-acryloyloxystearic acid, including the molar ratio of 12-hydroxystearic acid to acrylic acid, the catalyst amount, the esterification temperature, and the esterification time, were optimized. Under the optimized conditions, the 12-acryloyloxystearic acid with an acid value of 159 mg KOH/g and a melting range of between 70.4 ℃ and 71.4 ℃ was obtained. The structure of 12-acryloyloxystearic acid was confirmed by FTIR spectroscopy. Results of preparing magnesium 12-acryloyloxy stearate detergent showed the existence of acryloyloxy radical in 12-hydroxystearic acid could improve the quality of lubricant detergent greatly.
In this article, 12-acryloyloxystearic acid was synthesized, which was then used to prepare the magnesium 12-acryloyloxy stearate detergent. Reaction conditions for synthesizing 12-acryloyloxystearic acid, including the molar ratio of 12-hydroxystearic acid to acrylic acid, the catalyst amount, the esterification temperature, and the esterification time, were optimized. Under the optimized conditions, the 12-acryloyloxystearic acid with an acid value of 159 mgKOH/g and a melting range of between 70.4 ℃ and 71.4 ℃ was obtained. The structure of 12-acryloyloxystearic acid was confirmed by FTIR spectroscopy. Results of preparing magnesium 12-acryloyloxy stearate detergent showed the existence of acryloyloxy radical in 12-hydroxystearic acid could improve the quality of lubricant detergent greatly.
基金
This work was supported by the National Undergraduate Innovative Training Program(201410375004)
the Scientific Research Foundation for Introduced Scholars,Huangshan University(2015xkjq002)
the Scientific Research Foundation of Huangshan University(2014xkj012)
