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离子液体辅助合成Nd掺杂TiO_2的可见光催化性能

Visible-Light Photocatalytic Activity of Nd-Doped TiO_2 Synthesized with Ionic-Liquid Assistance
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摘要 在离子液体1-丁基-3-甲基咪唑四氟化硼([C4MIM]BF4)的辅助下,采用溶胶-凝胶法制备了Nd掺杂Ti O2光催化剂(Nd-Ti O2(IL))。实验结果表明:在加入[C4MIM]BF4、n(Nd)∶n(Ti O2)=2.5%的条件下制得的Nd-Ti O2(IL)(记作2.5%Nd-Ti O2(IL))的光催化性能最好;在初始亚甲基蓝质量浓度10 mg/L、2.5%Nd-Ti O2(IL)加入量1 g/L的条件下,光催化反应180 min,亚甲基蓝降解率为84%,2.5%Nd-Ti O2(IL)光催化降解亚甲基蓝的表观速率常数为0.010 9 min-1。表征结果显示:Nd的掺杂抑制了Ti O2晶粒长大,增大了Ti O2的比表面积,2.5%Nd-Ti O2(IL)的比表面积为80.77 m2/g;[C4MIM]BF4的加入提高了Ti O2的晶化度;Nd以Nd3+的形式,通过晶格取代方式进入Ti O2晶格。 The Nd doped TiO2 photocatalyst (Nd-TiO2 (IL)) was prepared by sol-gel method with assistance of ionic liquid [C4MIM] BF4. The experimental results show that: The photocatalyst prepared under the conditions of [C4MIM] BF4 addition and n (Nd) :n (TiO2) =2.5% (2.5%Nd-TiO2 (IL)) has the highest photocatalytic activity; When the initial mass concentration of methylene blue is 10 mg/L, the 2.5%Nd-TiO2 (IL) dosage is 1 g/L and the reaction time is 180 min, the degradation rate of methylene blue is 84%, the apparent rate constant on 2.5%Nd-TiO2 (IL) is 0.010 9 min-1. The characterization results show that: The doped Nd inhibits the growth ofTiO2 nanoparticles and increases the surface area of TiO2, the surface area of IL-2.5%Nd/TiO2 is 80.77 m2/g; The crystallinity of TiO2 is increased with the addition of [ C4MIM ] BF4; Nd3+ enters into the TiO2 lattice by lattice substitution.
出处 《化工环保》 CAS CSCD 北大核心 2015年第4期344-348,共5页 Environmental Protection of Chemical Industry
基金 国家自然科学基金项目(21173028) 辽宁省高等学校优秀科技人才支持计划项目(LR2012042) 大连市金州新区科技创新主体支持计划培育专项(KJCX-ZTPY-2014-0001)
关键词 钕掺杂 二氧化钛 离子液体 光催化剂 可见光催化 neodymium doping titanium dioxide ionic liquid photocatalyst visible-light photocatalysis
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