过渡金属催化法合成平面手性二茂铁衍生物的新进展

Recent Advances in Transition-Metal-Catalyzed Enantioselective Syntheses of Planar Chiral Ferrocenes

平面手性二茂铁衍生物已经发展成为不对称催化反应中一类良好的手性配体和手性催化剂.高效、高对映选择性的平面手性二茂铁衍生物合成方法研究是不对称催化研究的热点之一.综述了近年来利用过渡金属催化法合成面手性二茂铁衍生物的进展.

Planar chiral ferrocene derivatives have been proved to be effective ligands and catalysts in asymmetric catalysis. The study toward enantioselective synthesis of planar chiral ferrocenes became one of the high hot spots. In this paper, the recent advance in transition-metal-catalyzed menthods for the syntheses of planar chiral ferrocenes is reviewed.