几种典型羟基化多溴联苯醚和多溴联苯的合成、纯化及鉴定
被引量:1
摘要
通过耦合、氧化和溴化等基本有机化学反应,合成并纯化了几种典型羟基多溴联苯醚和多溴联苯.通过C18半制备高效液相色谱柱对反应粗成品进行分离与纯化,以气相色谱-质谱和氢谱核磁共振对产物进行结构鉴定与表征.结果表明,合成制备的产物与目标物一致,纯度达99%以上.
出处
《环境化学》
CAS
CSCD
北大核心
2015年第7期1377-1379,共3页
Environmental Chemistry
基金
国家自然科学基金(21277124
21477115)资助
参考文献5
-
1Lin K D, Yan C, Gan J. Production of hydroxylated polybrominated diphenyl ethers ( OH-PBDEs ) from bromophenols by manganese dioxide [ J ]. Environmental Science and Technology, 2014, 48 ( 1 ) : 263-271.
-
2Lin K D, Gan J, Liu W P. Production of hydroxylated polybrominated diphenyl ethers (HO-PBDEs) from bromophenols by bromoperoxidase-catalyzed dimerization [J]. Environmental Science and Technology, 2014, 48 (20) : 11977 - 11983.
-
3余海雯,张彰,李云娴,裘真.多溴联苯醚代谢产物的合成[J].环境化学,2008,27(5):615-619. 被引量:2
-
4Marsh G, Stenutz R, Bergman A. Synthesis of hydroxylated and methoxylated polybrominated diphenyl ethers natural products and potential polybrominated diphenyl ether metabolites[ J]. European Journal of Organic Chemistry, 2003:2566-2576.
-
5Marsh G, Athanasidou M, Athanassiadis I, et al. Identification, quantification, and synthesis of a novel dimethoxylated polybrominated biphenyl in marine mammals caught off the coast of Japan[ J]. Environmental Science and Technology, 2005, 39(22) : 8684-8690.
二级参考文献7
-
1Athanasiadou M, Marsh G, Athanassiadis I et al. , Gas Chromatography and Mass Spectrometry of Methoxylated Polybrominated Diphenyl Ethers (MeO-PBDEs) . Journal of Mass Spectrometry, 2006, 41:790-801
-
2Malmberg T, Athanasiadou M, Marsh Get al. , Identification of Hydroxylated Polybrominated Diphenyl Ether Metabolites in Blood Plasma from Polybrominated Diphenyl EtherExposed Rats. Environmental Science & Technology, 2005, 39:5342-5348
-
3Keum Y S, Li Q x, Reductive Debromination of Polybrominated Diphenyl Ethers and Organochlirines in Archived Northern Fur Seal Samples from the Pacific Coast of Japan, 1972-1998. Environmental Science and Technology, 2004, 38:3804-3809
-
4Darnerud P O, Eriksen G S, Polybrominated Diphenyl Ethers: Occurrence, Dietary Exposure, and Toxicology. Environ Health Persp. , 2001, 109:49-68
-
5Marsh G, Hu J, Jakobsson E et al. , Synthesis and Characterization of 32 Polybrominated Diphenyl Ethers. Environmental Science & Technology, 1999, 33:3033-3037
-
6Nilsson C, Norstrom A, Hansson Met al. , The Synthesis of Halogenated Diphenyliodonium Salts and Their Coupling Products with Halogenated Phenols. Chemosphere, 1997, 9:599-607
-
7Shoji K, Takaaki K, Hajime T et al. , Brominated of Phenols by Use of Benzyhrimethylammonium Tribromide. Chemistry Letters, 1987, 627-630
同被引文献30
-
1万云洋,杜予民.漆酶结构与催化机理[J].化学通报,2007,70(9):662-670. 被引量:48
-
2Cynthia A de Wit.An overview of brominated flame retardants in the environment[J]. Chemosphere . 2002 (5)
-
3Natalia N. Pozdnyakova,Janina Rodakiewicz-Nowak,Olga V. Turkovskaya,Jerzy Haber.Oxidative degradation of polyaromatic hydrocarbons catalyzed by blue laccase from Pleurotus ostreatus D1 in the presence of synthetic mediators[J]. Enzyme and Microbial Technology . 2006 (6)
-
4Lillemor Asplund,Maria Athanasiadou,Andreas Sjodin,Ake Bergman,Hans Borjeson.Organohalogen substances in muscle, egg and blood from healthy Baltic salmon (Salmo salar) and Baltic salmon that produced offspring with the M74 syndrome. Ambio . 1999
-
5Dingemans, Milou M L,Groot, Aart de,Kleef, Regina G D M van,Bergman, ?ke,Berg, Martin van den,Vijverberg, Henk P M,Westerink, Remco H S.??Hydroxylation Increases the Neurotoxic Potential of BDE-47 to Affect Exocytosis and Calcium Homeostasis in PC12 Cells(J)Environmental Health Perspectives . 2008 (5)
-
6Inhibition of human placental aromatase activity by hydroxylated polybrominated diphenyl ethers (OH-PBDEs)(J)Toxicology and Applied Pharmacology . 2007 (1)
-
7Jonathan Verreault,Geir W. Gabrielsen,Shaogang Chu,Derek C. G. Muir,Magnus Andersen,Ahmad Hamaed,Robert J. Letcher.Flame Retardants and Methoxylated and Hydroxylated Polybrominated Diphenyl Ethers in Two Norwegian Arctic Top Predators:? Glaucous Gulls and Polar Bears. Environmental Sciences . 2005
-
8Steen, Peter O.,Grandbois, Matthew,Mcneill, Kristopher,Arnold, William A.Photochemical formation of halogenated dioxins from hydroxylated polybrominated diphenyl ethers (OH-PBDEs) and chlorinated derivatives (OH-PBCDEs). Environmental Sciences . 2009
-
9Hooper K,McDonald T A.The PBDEs: an emerging environmental challenge and another reason for breast-milk monitoring programs. Journal of Environmental Health . 2000
-
10Shigeyuki Takagi,Chiaki Shirota,Kazuko Sakaguchi,Jun Suzuki,Takumi Sue,Hiromitsu Nagasaka,Shin Hisamatsu,Shigenori Sonoki.??Exoenzymes of Trametes versicolor can metabolize coplanar PCB congeners and hydroxy PCB(J)Chemosphere . 2006 (9)
-
1宋亮辉.漆酶降解羟基多溴联苯醚反应动力学及产物[J].轻工科技,2016,32(5):29-32. 被引量:1
-
2孙粉玲,丁佳锋,周时洋,林坤德.针铁矿催化氧化溴酚生成羟基多溴联苯醚和溴代二噁英[J].环境化学,2015,34(9):1581-1586. 被引量:1
-
3崔庆华,杨晓勇,赵桂安.邻甲苯胺及其同分异构体的分离[J].纺织标准与质量,2012(1):37-41. 被引量:1
-
4王英,丁问微,金军.超高效液相色谱-电喷雾离子源-串联三重四极杆质谱分析人血中羟基多溴联苯醚[J].分析化学,2011,39(1):22-26. 被引量:7
-
5左国强,李全民,张毅军,范立群,张裕平.分子印迹液相色谱整体柱的制备和应用[J].河南科技学院学报,2007,35(1):37-41. 被引量:3
-
6刘明仁,杨学雨,张昭良.气相色谱质谱-内标法检测染发剂中苯二胺[J].环境化学,2010,29(1):139-140. 被引量:12
-
7李敏洁,金芬,杨莉莉,乌日娜,邵华,金茂俊,王静.凝胶渗透色谱-分散固相萃取法同时测定鸡蛋中多溴联苯醚及其衍生物、四溴双酚A和六溴环十二烷[J].分析化学,2014,42(9):1288-1294. 被引量:11
-
8井文杰,巨文军,翁薇,张航,王洋.邻苯二甲酸二丁酯中有机硫含量的测定[J].化学推进剂与高分子材料,2012,10(6):83-85.
-
9贲玉婕,李龙,王文月,李兴红,田媛,徐晓白.母乳中溴代/氯代阻燃剂及其代谢产物的分析检测方法[J].分析化学,2013,41(1):69-75. 被引量:3
-
10毛树禄,张元金,李小娅,尤志勇,尹洪雷,陈斌.气相色谱-质谱法测定塑料产品中三(2-氯乙基)磷酸酯的含量[J].福建分析测试,2014,23(1):9-12. 被引量:2