期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

脱硫化反应在汞离子传感器中的应用进展 被引量：1

Applications progress of desulfurization reaction in chemosensors for mercury ion
下载PDF
导出
摘要 汞离子具有独特的嗜硫性,因此脱硫化反应被广泛地应用于汞离子传感器的设计之中,并表现出超高的选择性。本文在前期研究工作的基础上,结合相关文献报道,综述了脱硫化反应在汞离子化学传感器中的应用,包括汞离子与硫代羰基化合物发生脱硫反应、汞诱导硫脲衍生物脱硫化氢生成胍类化合物的反应、汞诱导的方酸化合物脱硫醇反应、汞促进氨基硫脲转化为二唑反应以及缩硫醛化合物的脱保护反应。分析文献表明,该领域的研究目前仍存在一些尚未解决的问题:有些化学反应的反应条件较苛刻;有些化学反应在室温下反应速率较慢;一些传感体系对汞离子检测的灵敏度较低。因此,需要更好地利用化学反应,探索并优化传感条件,为反应型汞离子传感器的发展提供更多契机。 Because of the thiophiolic property of mercury ions, desulfurization reactions have been widely used in the design of reactive sensors for mercury ions and provide us methods of investigating mercury ions with superior selectivity. This review mainly focused on the applications of desulfurization reactions in the design of chemosensers for mercury ions, including the HgZ＋-promoted desulfurization reactions of thiocarbonyl compounds, derivatives of thiourea, squaraine-based compounds, thiosemicarbazide compounds, as well as the Hg2＋-promoted deprotection of dithioacetals. Several obstacles in this field include harsh reaction conditions for some chemical reactions in the design of sensors of mercury ions, slow reaction rate of some chemical reactions at room temperature; low sensitivity of some sensor systems. Therefore, optimization of the sensing conditions is needed in order to provide more opportunities in the development of reactive sensors for mercury ions.
作者 程晓红 王松
机构地区 湖北文理学院低维光电材料与器件湖北省重点实验室 湖北文理学院物理与电子工程学院
出处 《化工进展》 EI CAS CSCD 北大核心 2015年第8期2925-2931,共7页 Chemical Industry and Engineering Progress
基金 国家自然科学基金项目(21401053) 湖北文理学院博士科研基金项目 低维光电材料与器件湖北省重点实验室开放课题项目(HLOM 142012)
关键词 有机化合物 传感器 选择性 化学反应 汞离子 organic compounds sensors selectivity chemical reaction mercury
分类号 O622.4 [理学—有机化学]
  • 相关文献

参考文献33

  • 1舒杰明,高云玲,姚克俭,胡颖.香豆素类荧光传感器检测金属离子的研究进展[J].化工进展,2014,33(12):3144-3156. 被引量：18
  • 2de Silva AP, Gunaratne H Q N, Gunnlaugsson T, et al. Signaling recognition events with fluorescent sensors and switches[J]. Chem. Rev., 1997, 97: 1515-1566.
  • 3Kim J S, Quang D T. Calixarene-derived fluorescent probes[J]. Chem. Rev., 2007, 107: 3780-3799.
  • 4Kim S K, Lee S H, Lee J Y, et al. An excimer-based, binuclear, on-offswitchable ealix[4]crown chemosensor[J]. J. Am. Chem. Soc., 2004, 126: 16499-16506.
  • 5Matsushita M, Meijler M M, Wirsching P, et al. A blue fluorescent antibody-cofactor sensor for mercury[J]. Org. Lett., 2005, 7 : 4943-4946.
  • 6Chae M Y, Czarnik A W. Fluorometric chemodosimetry. Mercury( II ) and silver(l) indication in water via enhanced fluorescence signaling[J]. J. Am. Chem. Soc., 1992, 114: 9704-9705.
  • 7Cho D G, Sessler J L. Modem reaction-based indicator systems[J]. Chem. Soc. Rev., 2009, 38: 1647-1662.
  • 8Du J, Hu M, Fan J, et al. Fluorescent chemodosimeters using "mild" chemical events for the detection of small anions and cations in biological and environmental media[J]. Chem. Soc. Rev., 2012, 41: 4511-4535.
  • 9冷冰,田禾.反应型汞离子光化学传感器[J].化学进展,2010,22(5):837-844. 被引量：3
  • 10Jun M E, Roy B, Ahn K H. "Turn-on" fluorescent sensing with "reactive"probes[J]. Chem. Commun., 2011, 47: 7583-7601.

二级参考文献97

  • 1孟祥明,刘磊,郭庆祥.铅、汞、镉离子的荧光传感器研究进展[J].化学进展,2005,17(1):45-54. 被引量：19
  • 2Nolan E M, Lippard S J. Chem. Rev. , 2008, 108(9) : 3443- 3480.
  • 3Prodi L, Bargossi C, Montahi M, Zaccheroni N, Su N, Bradshaw J S, Izatt R M, Savage P B. J. Am. Chem. Soc., 2000, 122(28) : 6769-6770.
  • 4Guo Z, Zhu W, Shen L, Tian H. Angew. Chem. Int. Ed. , 2007, 46(29) : 5549-5553.
  • 5Yuan M, Li Y, Li J, Li C, Liu X, Lv J, Xu J, Liu H, Wang S, Zhu D. Org. Lett. , 2007, 9(12) : 2313-2316.
  • 6Descalzo A B, Martinez-Manez R, Radeglia R, Rurack K, Soto J. J. Am. Chem. Soc., 2003, 125(12): 3418-3419.
  • 7Wang Z, Zhang D, Zhu D. Anal. Chim. Acta, 2005, 549(1/ 2) : 10-13.
  • 8Kim J S, Choi M G, Song K C, No K T, Ahn S, Chang S K. Org. Lett. , 2007, 9(6) : 1129-1132.
  • 9Othman A B, Lee J W, Wu J S, Kim J S, Abidi R, Thuery P, Strub J M, Dorsselaer A V, Vicens J. J. Org. Chem. , 2007, 72(20) : 7634-7640.
  • 10Coskun A, Akkaya E U. J. Am. Chem. Soc., 2006, 128 (45) : 14474-14475.

共引文献19

同被引文献40

  • 1马文辉,彭孝军,徐群,宋波.香豆素类荧光传感器[J].化学进展,2007,19(9):1258-1266. 被引量：48
  • 2CHO D G, SESSLER J L. Modern reaction-based indicator systems[J]. Chemical Society Reviews, 2009, 38 (6): 1647-1662.
  • 3MIEUN Jun, BASAB Roy, KYO Han Ahn. "Turn-on" fluorescent sensing with "reactive" probes[J]. Chemical Communications, 2011, 47 (27): 7583-7601.
  • 4CHAN J , DODANI S C, CHANG C J. Reaction-based small-molecule fluorescent probes for chemoselective bioimaging[J]. Nature Cheinistry, 2012, 4 (12): 973-984.
  • 5YAN M, HONG M, LIU A, et al. Highly selective and sensitive detection of Hg( 11 ) from HgCI_, by a simple rhodamine-based fluorescent sensor.[J]. Journal of Fluorescence, 2015, 25 (3): 1-7.
  • 6CHEN Y, YANG C, YU Z, et al. A highly sensitive hemicyanine-based fluorescent chemodosimeter for mercury ions in aqueous solution and living cells[J]. RSC Advances, 2015, 5: 82531-82534.
  • 7WANG F H, CHENG C W, DUAN L C, et al. Highly selective fluorescent sensor for Hg2+ ion based on a novel rhodamine Bderivative[J]. Sensors & Actuators B Chemical, 2015, 206: 679-683.
  • 8SUMIYA S , SUGII T , SHIRAISHI Y , et al. A benzoxadiazole-thiourea conjugate as a fluorescent chemodosimeter for Hg( lI ) in aqueous media[J]. Joumal of Photochemistry & PhotobiologyA Chemistry, 2011, 219 (1): 154-158.
  • 9JIANG H, LUO W, JIANG J, et al. A resumable two-photon fluorescent chemodosimeter for Hg2+ in aqueous solution[J]. Sensors &Actuators BChemical, 2014, 204: 68-73.
  • 10LEE H, KIM H J. Ratiometric fluorescence chemodosimeter for mercuric ions through the Hg( II )-mediated propargyl amide to oxazole transformation[J]. Tetrahedron Letters, 2011, 52 (37): 4775-4778.

引证文献1

二级引证文献7

化工进展
2015年 第8期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部