摘要
利用邻氯苯甲酸和邻苯二胺发生阿尔曼偶联反应,产物经PPA脱水,亲核加成得到一种未见报道的新型4-[4-(N,N-二苯基)苄亚甲基]氨基吖啶酮产物。化合物的结构经红外、氢谱进行了确认,并对这种化合物的紫外、荧光和电化学性质进行了研究。结果表明:(1)新型化合物的荧光性能并不优良,由于结构的特殊性,所以经进一步修饰可能成为优良的化学传感器;(2)新型化合物的能带隙很小,说明此新型化合物电子传输所需的能量较小,有望发展成为导体化合物。
4-[（4-（diphenylamino） benzyldene）amino]acridone was synthesized by o-chlorobenzoic acid reacted with o-phenylenediamine,dehydrated in heated PPA, nucleophilic addition, the structures of compounds were confirmed by IR,1 H-NMR. Following the uv-vis, fluorescence, electrochemistry properties of the compounds were studied. The experi- mental results indicated：l, the fluorescence performance of novel compound was not excellent, due to the structure was spe- cial,so after further modification it might become better chemical sensors. 2. energy band gap of this compound was very narrow,electronic transmission required little energy,so the novel compound was expected to develop to a conductor.
出处
《化工新型材料》
CAS
CSCD
北大核心
2015年第8期109-111,共3页
New Chemical Materials
基金
徐州工程学院青年教师科研专项基金(XKY2014312)
