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氮掺杂TiO_2/壳聚糖复合膜吸附和光降解染料(英文) 被引量:9

Adsorption and photocatalytic degradation of dye by N-doped TiO_2/chitosan composited films
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摘要 氮掺杂二氧化钛/壳聚糖(CS)复合膜是一种有前途的有机染料废水处理材料,相对于传统的废水处理材料更具优势。在模拟太阳光照射下,用氮掺杂二氧化钛/壳聚糖(CS)复合膜对有机染料甲基橙溶液进行降解,通过吸附和光催化的双重作用,甲基橙的降解率可达99%。采用X射线衍射(XRD)、扫描电子显微镜(SEM)等对复合膜进行了表征,并通过傅里叶红外光谱(FT-IR)分析表明其壳聚糖中活性官能团NH2,OH在氮掺杂TiO2复合膜中同时存在。研究表明,氮掺杂二氧化钛/壳聚糖(CS)复合膜是一种高效节能的污水处理材料。 A novel N-doped TiO2/Chitosan (CS) composited film, as a promising alternative material, was prepared, and could be more potential compared with tradition materials for treating wastewater. When this material, N-doped TiO2/CS film, was used for removing Methyl Orange (MO) under simulated solar light irradiation, about 99% of total MO removal was achieved due to the combination effect of photo-degradation and adsorption processes. N-doped TiO2/CS photo-catalyst was characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FT-IR) analysis. The results indicate that there exist the reactive groups NH2, OH on the N-doped TiO2 film, and their contents in the prepared photo-catalyst are responsible for the photo-degradation and adsorption effect, which was confirmed by FT-IR. Hence, it is possible that using N-doped TiO2/ CS film as a simple method for removal of the pollutants in wastewater.
出处 《化工学报》 EI CAS CSCD 北大核心 2015年第9期3746-3752,共7页 CIESC Journal
基金 supported by the National Natural Science Foundation of China(51309074,21476059,21276063)~~
关键词 N-TiO2 壳聚糖 纳米颗粒 复合膜 降解 N-TiO2 chitosan nanoparticles composited film degradation
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  • 1Kong M, Chen X, Liu C, Liu C, Meng X, Yu L. Bactericidal mecha?nism of CS microspheres in a solid dispersing system against E. coli[J]. Colloid Surface B, 2008, 65 (2): 197-202.
  • 2Laus R, Favere V T de. Competitive adsorption of Cu (11) and Cd (11) ions by chitosan crosslinked with epichlorohydrin-triphosphate[J]. Bioresource Technology, 2011, 102 (19): 8769-8776.
  • 3Kushwaha S, Sudhakar P P. Adsorption of mercury (11), methyl mer?cury (11) and phenyl mercury (11) on chitosan cross-linked with a barbital derivative Pl. Carbohydrate Polymers, 2011, 86 (2): 1055-1062.
  • 4Zainal Z, Hui L K, Hussein M Z. Characterization of Ti02-chitosanl glass photocatalyst for the removal of a monoazo dye via photode?gradation-adsorption process[J]. Journal of Hazardous Materials, 2011,164 (1): 138-145.
  • 5Ngah WSW, Fatinathan S, Yosop N A. Isotherm and kinetic studies on the adsorption of humic acid onto chitosan-H2S04 beads Pl. De?salination, 2011, 272 (1-3): 293-300.
  • 6Huang X Y, Bu H T, Jiang G B, Zeng M H. Cross-linked succinyl chitosan as an adsorbent for the removal of Methylene Blue from aqueous solution[J]. International Journal of Biological Macro?molecules, 2011, 49 (4): 643-651.
  • 7Liu L F, Zhang P H, Yang F L. Adsorptive removal of 2,4-DCP from water by fresh or regenerated chitosanlACF/Ti02 membrane[J]. Separation and Purification Technology, 2011, 70 (3): 354-361.
  • 8Kumari A, Yadav S K, Yadav S C. Biodegradable polymeric nanopar?tides based drug delivery systems[J]. Colloid Surface B, 2010, 75 (1): 1-18.
  • 9Wang H J, Zhao P Q, Liang X F, Gong X Q, Song T, Niu R F, Chang J. Folate-PEG coated cationic modified chitosan-Cholesterol lipo?somes for tumor-targeted drug delivery[J]. Biomaterials, 2010, 31 (14): 4129-4138.
  • 10Wan Ngaha W S, Teong L C, Hanafiah M A K M. Adsorption of dyes and heavy metal ions by chitosan composites[J]. Carbohydrate Polymers, 2011, 83 (4): 1446-1456.

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