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磺化杯[6]芳烃的合成表征及热性能研究 被引量：1

Synthesis and Thermal Properties of Sulfonated Calix[6]arene
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摘要 以杯[6]芳烃为原料,在浓硫酸催化作用下,合成了磺化杯[6]芳烃,并通过红外光谱和核磁共振谱对其进行结构表征。热重分析结果表明,在升温速率为5℃/min时,磺化杯[6]芳烃开始降解温度为125.62℃,最快降解温度为269.43℃。经过Kissinger方程计算,磺化杯[6]芳烃的降解活化能为161.45k J/mol。 Sulfonated calix[6]arene was successfully synthesized from calix[6]arene using H2SO4 as catalyst. Structure of sulfonated calix[6]arene was characterized by FTIR and 1H NMR. TGA curves of sulfonated calix[6] arene indicated that the starting decomposition temperature of sulfonated calix[6]arene was 125. 62℃,and the fast decomposition temperature was 269. 43℃. According to Kissinger equation,the thermal decomposition Ea of sulfon-ated calix[6]arene was 161. 45kJ/mol.
作者 戴春燕 吴通明 詹国峰 张志辉 庞慧颖 吴仁东 王倩 朱林华
机构地区 海南师范大学化学与化工学院 嘉力丰实业股份有限公司 浙江树人大学生物与环境工程学院
出处 《合成材料老化与应用》 2015年第4期90-92,125,共4页 Synthetic Materials Aging and Application
基金 海南省自然科学基金项目(214026)
关键词 磺化杯6芳烃 合成 热降解 sulfonated calix[6] arene synthesis thermal degradation
分类号 TQ325.1 [化学工程—合成树脂塑料工业]
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参考文献9

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合成材料老化与应用
2015年 第4期

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