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Thermal stability and spectroscopic properties of Ho^(3+) doped tellurite-borate glasses 被引量:1

Thermal stability and spectroscopic properties of Ho^(3+) doped tellurite-borate glasses
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摘要 Ho3+ ions doped tellurite-borate glass samples with varying compositions were prepared. The compositional dependence on phenomenological Judd-Ofelt parameters was compared in different kinds of rare earth ions doped tellurite-borate glasses. Two methods were used to obtain radiative transition probability of 517 level with the aim of assuring the fitting quality. The integral absorption cross-sections and line shapes corresponding to 518--.5G6 and 518---5I7 transition of Ho3+ ions were investigated in tellurite-borate glasses. The obtained data indicated that the integral absorption cross-sections corresponding to 518-5G6 transition of Ho3+ ions mainly depended on phenomenological Judd-Ofelt parameter, g22, because 518---5G6 transition belonged to hypersensitive transitions, which led to a larger gP2 value. The change of line shapes of absorption spectra corresponding to 518-5G6 and 518-517 transitions of Ho3+ ions came from the lower energy regions, which could be attributed to the changed distribution of Stark levels and thermal population. Ho3+ ions doped tellurite-borate glass samples with varying compositions were prepared. The compositional dependence on phenomenological Judd-Ofelt parameters was compared in different kinds of rare earth ions doped tellurite-borate glasses. Two methods were used to obtain radiative transition probability of 517 level with the aim of assuring the fitting quality. The integral absorption cross-sections and line shapes corresponding to 518--.5G6 and 518---5I7 transition of Ho3+ ions were investigated in tellurite-borate glasses. The obtained data indicated that the integral absorption cross-sections corresponding to 518-5G6 transition of Ho3+ ions mainly depended on phenomenological Judd-Ofelt parameter, g22, because 518---5G6 transition belonged to hypersensitive transitions, which led to a larger gP2 value. The change of line shapes of absorption spectra corresponding to 518-5G6 and 518-517 transitions of Ho3+ ions came from the lower energy regions, which could be attributed to the changed distribution of Stark levels and thermal population.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2015年第9期939-945,共7页 稀土学报(英文版)
基金 supported by the National Natural Science Foundation of China(50902042) the Natural Science Foundation from Education Department of Hebei Province(ZD2014069)
关键词 Ho3+ tellurite-borate glasses cross sections line shapes rare earths Ho3+ tellurite-borate glasses cross sections line shapes rare earths
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