摘要
多钒氧簇由于具有组成、结构和尺寸易于调控、氧化还原性以及低腐蚀性等优点,在光电、磁性、催化以及医药等领域具有广阔的应用前景,已成为多酸化学领域的研究热点之一。本文结合近年来国内外及本课题组关于多钒氧簇化学的研究,综述了多钒氧簇的合成、结构及性能研究进展,并对未来发展趋势进行了展望。
Due to the advantages of their regulated composition, structure and size, redox activity and low corrosivity, etc., polyoxovanadium clusters have broad application prospects in the field of optical, magnetic, catalytic, medicine and become one of the hot research topics of polyoxometalates chemistry. Based on the recent investigations, this paper summarizes the related advancements in the synthesis, structure and properties of polyoxovanadium clusters and gives their researching prospects.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2015年第9期1705-1725,共21页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.21173021,21231002和21276026)
111课题(No.B07012)
973项目(No.2014CB932103)
山东省自然科学基金(No.ZR2013BL012)资助项目
关键词
多钒氧簇
有机官能化
杂化
性质
应用
polyoxovanadium clusters
organofunctionalized
hybrid
properties
application