含有轴向配体的酞菁金属材料的合成与应用进展

Progresses in Synthesis and Application of Metal Phthalocyanines with Axial Ligands

近几年含有轴向配体的酞菁金属材料的合成与应用取得突飞猛进的发展,尤其在太阳能电池材料方面的研究与应用更为显著。介绍了含有轴向配体的酞菁金属配合物的结构特征,阐述了这类酞菁金属材料在合成方面的研究进展以及在催化氧化、光盘信息记录、太阳能电池、医学等领域的应用进展,并对其发展前景进行了展望。

Metal phthalocyanines with axial ligands are a kind of coordination compounds with the axial ligands coordinated to central metallic atoms. The two-dimensional macrocyclic conjugated electronic systems can improve the solubility,stability and optoelectr onic properties of the phthalocyanines. In recent years,great achievements have been made in the synthesis and application of the metal phthalocyanines with the axial ligands,especially in the field of solar cell materials. The structure characteristics and synthesis of the metal phthalocyanines with the axial ligands,as well as their application in catalytic oxidation,optical information recording,nonlinear optics,solar cell and medicine,were reviewed. Their development prospects were discussed.