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PEMFC极化曲线半经验模型的改进 被引量:5

Semi-empirical model improving for polarization curve of PEMFC
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摘要 根据实验测得的数据,对燃料电池的极化曲线进行特性分析,归纳建模方法,在Kim模型和Fraser模型的基础上,针对小电流密度区间拟合精度低和拟合参数过多的问题,修正了活化损耗项,提出了改进的半经验模型。比较3个模型拟合结果的鲁棒性和精确性,建立的半经验模型拟合精度更高,实用性更强。 Based on the measured data, the polarization curve characteristics of fuel cells were analyzed, the modeling methods were summarized. To raise low current density fitting accuracy and reduce fitting parameters, activation loss items were fixed, thereby an improved semi-empirical model derived from Kim model and Fraser model was proposed. The robustness and accuracy of fitting results of the three models were compared. The improved semi-empirical model had a better accuracy and higher practicality.
出处 《电池》 CAS CSCD 北大核心 2015年第4期179-181,共3页 Battery Bimonthly
基金 国家自然科学基金(51275357)
关键词 燃料电池 极化曲线 半经验模型 fuel cell polarization curve semi-empirical model
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参考文献5

  • 1Kim J,Lee S, Srinivasan S, et al. Modeling of proton exchangemembrane fuel cell performance with an empirical equation[ J]. JElectrochem Soc, 1995,142(8) ;2 670 -2 674.
  • 2Chu D, Jiang R, Walker C. Analysis of PEM fuel cell stacks usingan empirical voltage-current equation [ J]. J Appl Electrochem,2000,30(3) :365 -370.
  • 3Fraser S D,Hacker V. An empirical fuel cell polarization curve fit-ting equation for small current densities and no-load operation [ J ].J Appl Electrochem,2008,38(4) :451 -456.
  • 4Weydahl H,Moller-Holst S,Hagen G et al. Transient response of aproton exchange membrane fuel cell[ J]. J Power Sources,2007 ,171 :321 -330.
  • 5Poh C K,Lim S H,Pan H,et al. Citric acid functionalized carbonmaterials for fuel cell applications[ J]. J Power Sources,2008,176:70-75.

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