摘要
A low band gap acceptor-donor-acceptor (A-D-A) small molecule donor material, named DR3TDTN, has been designed and synthesized for solution-processed organic solar cells. DR3TDTN shows narrow optical band gap with value of 1.49 eV and broad absorption spectrum from 300 to 820 rim. The HOMO and LUMO energy levels of DR3TDTN are -4.74 and -3.26 eV, respectively. The optimized photovoltaic device based on DR3TDTN:PC71BM blend film shows a power conversion efficiency of 3.03% with an open-circuit voltage of 0.67 V, a short-circuit current of 8.22 mA·cm^-2 and fill factor of 0.55.
A low band gap acceptor-donor-acceptor (A-D-A) small molecule donor material, named DR3TDTN, has been designed and synthesized for solution-processed organic solar cells. DR3TDTN shows narrow optical band gap with value of 1.49 eV and broad absorption spectrum from 300 to 820 rim. The HOMO and LUMO energy levels of DR3TDTN are -4.74 and -3.26 eV, respectively. The optimized photovoltaic device based on DR3TDTN:PC71BM blend film shows a power conversion efficiency of 3.03% with an open-circuit voltage of 0.67 V, a short-circuit current of 8.22 mA·cm^-2 and fill factor of 0.55.