摘要
利用传统的方法合成了3种不同结构的吖啶酮类衍生物:10-苯基吖啶酮、苯并吖啶酮、二苯并吖啶酮,其中二苯并吖啶酮为首次合成的新型化合物,化合物的结构经红外、氢谱、碳谱进行确认,并对这3种化合物的紫外、荧光、电化学性质进行了研究。研究证明10-苯基吖啶酮、苯并吖啶酮具有较好的荧光性能,3种化合物都具有较高的电子亲和势,说明3种化合物都具有较好的电子传输能力。
Three acridone derivatives were synthesized according to traditional methods： 10-phenylacridone, benzo[c]acridin-7（12H）-one and dibenzo[a,c] acridin-14（9H）-one, among them benzo[a,c]acridin-4（gH）-one was firstly reported. The structures of compounds were confirmed by IR,^1H NMR and ^13C NMR, and subsequently the properties of UV-Vis, fluorescence, electrochemistry were studied. The results showed that both 10-phenylacridone and benzo[c]acridin-7（12H）-one have good fluorescence property, all of three compounds with high electron affinity, that three kinds of compounds have good electronic transmission.
关键词
吖啶酮类化合物
结构确认
光电性质
acridone derivatives, structure confirmation, photoelectric performance
