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2-羟基-3-甲氧基苯甲醛异烟酰腙配合物的合成及荧光性能研究 被引量：2

Synthesis,Flourescence Properties of 3-Methoxy 2-Hydroxy Benzaldehyde Isoniazid Hydrazoe and Its Complexes
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摘要 利用异烟酰肼和2-羟基-3-甲氧基苯甲醛(邻香草醛)合成了一种新的Schiff碱-2-羟基-3-甲氧基苯甲醛异烟酰腙(L),并制备其Cu(Ⅱ)、Cd(Ⅱ)、Zn(Ⅱ)的配合物。利用元素分析、摩尔电导、红外光谱、紫外光谱、差热分析等手段对该Schiff碱及其配合物进行了表征,得到了Schiff碱及其配合物的推测组成,并研究了配体和配合物的荧光光谱,结果表明锌和镉的配合物与配体相比具有较好的荧光特性。 A series of Cu（ Ⅱ）, Cd（ Ⅱ ） and Zn（ Ⅱ ） complexes were synthesized and designed by reactions of andisonicotinic acid hydrazide and orthovanilline. All the complexes were characterized by a number of analytical techniques. Luminescence properties of these polynuclear complexes were investigated and discussed. The results showed that zinc and cadmium complexes have good fluorescence properties.
作者 田军 乔秀丽 董艳萍
机构地区 绥化学院食品与制药工程学院
出处 《材料导报（纳米与新材料专辑）》 EI CAS 2015年第1期205-209,共5页
基金 绥化学院科学技术研究项目(K1301005)
关键词 异烟酰腙 SCHIFF碱 配合物 荧光 isoniazid hydrazoe, Schiff base, complex, fluorescence
分类号 O622.5 [理学—有机化学]
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参考文献15

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材料导报（纳米与新材料专辑）
2015年 第1期

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