摘要
综述了Salen系列手性配体及Salen型手性金属配合物催化剂的合成过程和发展历程以及应用。Salen-M是一种用途广泛、性能优异的手性催化剂,可用于多种化学反应,且其合成相对廉价和简单。展望了Salen型手性金属配合物催化剂在手性合成中的应用前景和发展方向。
Series chiral Salen ligand and Salen-type chiral metal complexes as catalysts for synthesis processes and their development and application are reviewed, Salen-M is a widely used chiral catalyst with excellent properties, can be used for a variety of chemical reactions, and is relatively cheap and simple to synthesize. Salen-type Chiral metal complexes as catalysts in synthesis of chiral shows broad application prospects and development direction.
基金
国家大学生创新创业训练计划项目(201411059018)
国家自然科学基金(21376059)