期刊文献+

铁素体不锈钢在盐酸基溶液中的加速腐蚀行为研究 被引量:6

Experimental Studies on Corrosion Behaviour of Ferritic Stainless Steel in HCl Based Solution
原文传递
导出
摘要 以抛丸后的热轧430铁素体不锈钢板为原料,通过酸洗模拟试验,结合腐蚀失重测定、微观形貌分析、极化曲线及交流阻抗谱测试,研究了氧化剂氯酸钾(KCl O3)对铁素体不锈钢盐酸基酸洗过程及板面质量的影响作用规律。试验结果表明:KCl O3可以通过加速阴极反应速率,减小电荷转移电阻,从而明显加速铁素体不锈钢的酸洗进程,但过量加入时易产生点蚀倾向。KCl O3可以作为适用于铁素体不锈钢盐酸基酸洗盐酸工艺的合理氧化剂,其适宜的加入量为1%。 The effect of potassium chlorate( KCl O3) as oxidants on pickling behaviour in HCl-based electrolyte and the surface quality of original hot-rolled and blasted 430 stainless steel( 430- SS) were studied,by means of weight-loss tests,microstructure analyses,potentiodynamic polarization curves and electrochemical impedance spectroscopy measurements. The results showed significantly accelerated pickling process for 430- SS happened by adding KCl O3 through enhanced cathodic reaction rate and reduced Rt,with pitting corrosion when excess KCl O3 was added. KCl O3 is a proper oxidant for pickling in HCl-based electrolyte of 430- SS,with reasonable addition of 1%.
机构地区 东北大学
出处 《钢铁钒钛》 CAS 北大核心 2015年第4期114-118,共5页 Iron Steel Vanadium Titanium
基金 国家自然科学基金(51374060) 辽宁省科技攻关项目(2012221013)
关键词 铁素体不锈钢 盐酸酸洗 腐蚀行为 极化曲线 阻抗图谱 氯酸钾 ferritic stainless steel HCl pickling corrosion behavior polarization curve EIS KClO3
  • 相关文献

参考文献8

  • 1Li L F, Caenen P, Jiang M F. Electrolytic pickling of the oxide layer on hot-rolled 304 stainless steel in sodium supphate[J]. Corrosion Science, 2008, 50(10) : 2824-2830.
  • 2Li L F, Caenen P, Celis J P. Chemical pickling of 304 stainless steel in fluoride and sulfate containing acidic electrolytes [ J ]. Journal of The Electrochemical Society, 2005, 152(9) : 352-357.
  • 3Bitondo C, Bossio A, Monetta T, et aL The effect of annealing on the corrosion behaviour of 444 stainless steel for drinking wa- ter applications[J]. Corrosion Science, 2014, 87: 6-10.
  • 4Tumbull A, Mingard K, Lord J D, et al. Sensitivity of stress corrosion cracking of stainless steel to surface machining and grinding procedure [J]. Corrosion Science, 2011, 53 (10): 3398-3415.
  • 5Jiang M F, Li X L, Yue Y Y, et al. Effect of hydrochloric acid on electrochemical behavior of 430 stainless steel [J]. Materi- als Research Innovations, 2014, 18(S5) : 62-65.
  • 6李晓亮,史培阳,岳莹莹,姜茂发.盐酸浓度对热轧不锈钢酸洗板表面质量的影响[J].东北大学学报(自然科学版),2014,35(11):1548-1551. 被引量:6
  • 7Brigitta W, Edgar B. Gerald M. Process of pickling stainless steel,USA: US6250314B1 [P. 2001-06-26.
  • 8Joseph C, Peterson. Rinse aid and process for stainless steel, USA. US5821212A [ P]. 1998-10-13.

二级参考文献11

  • 1林百春.不锈钢表面处理:酸洗、钝化与抛光[J].材料开发与应用,2006,21(3):36-39. 被引量:29
  • 2闫莹,李伟华,邢少华,侯保荣.新型杂环化合物在1mol/L HCl中对Q235钢的缓蚀性能研究[J].腐蚀科学与防护技术,2007,19(6):414-418. 被引量:17
  • 3Ponto L, Datta M,Landolt D. Electropolishing of iron-chromium alloys in phosphoric acid-sulphuric acidelectrolytes [ J ]. Surface and Coatings Technology, 1987,30:265 -276.
  • 4Narvaez L, Cano E, Bastidas J M. Hydrogen peroxidedecomposition in an environmentally friendly picking solutionfor AISI 316L stainless steel[ J]. Corrosion Science,2005,1(61):21 -29.
  • 5Sanders N J. Environmentally friendly stainless steel pickling[J]. Anti-Corrosion Methods and Materials,1997,44 (1 ):20-25.
  • 6Hudson R M, Warning C J. Pickling hot rolled steel stripeffect of strip velocity on rate in H2 S04 [ J ]. MetalFinishing:39 -46.
  • 7Ellison B T, Schmeal W R. Corrosion of steel in concentratedsulfuric acid [ J ]. Journal of the Electrochemical Society,1978,125(4) :524 -531.
  • 8Li L F, Caenen P, Jiang M. Electrolytic pickling of the oxidelayer on hot-rolled 304 stainless steel in sodium sulphate[ J].Corrosion Science,200S ,50( 10) :2824 - 2830.
  • 9Hermoso J, Dufour J, Galvez i L, et al. Nickel hydroxiderecovery from stainless steel pickling liquors by selectiveprecipitation [ J ]. Industrial and Engineering ChemistryResearch,2005,44(15) :5750 -5756.
  • 10Abd S S, Sayyah S M, El-Deeb M M. Poly ( o-phenylenediamine) as an inhibitor of mild steel corrosion inHC1 solutionf J]. Materials Chemistry and Physics,20^0,\23(1):20 -27.

共引文献5

同被引文献47

引证文献6

二级引证文献7

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部