期刊文献+

丙二酸酯类化合物脱羧反应应用于工业上的优劣比较 被引量:1

Comparison of Decarboxylation Reaction of Malonic Acid Ester Compounds in Industry
下载PDF
导出
摘要 对丙二酸酯类化合物脱羧反应应用于工业上的优劣进行了比较,工业化实践表明,热解脱羧法收率最高,经工业化验证,产品总收率达到95%,比文献收率提高了约30个百分点。 s: Different decarboxylation methods of malonic acid ester compounds in industry was compared. It was showed that the pyrolysis of decarboxylation method gave the best result which was also testified by scaling up in industry. The yield increased from 63 % to 95 % totally, which was compared with the document.
出处 《广东化工》 CAS 2015年第17期59-59,63,共2页 Guangdong Chemical Industry
关键词 丙二酸酯类化合物 脱羧反应 工业化 malonic acid ester decarboxylation scaling up
  • 相关文献

参考文献3

  • 1Alexander Z Voskoboynikov, Vyatcheslav V lzmer, Andrey F Asachenko. Heteroatom Bridged Metallocene Compounds for Olefin Polymerization, US, 2007/0135597[P]. 2007-06-14.
  • 2Adamczyk Maciej, Watt David S, Netzel Daniel A. Synthesis of biological markers in fossil fuels. 2. Synthesis and carbon-13 NMR studies of substituted indans and tetralins[J]. Journal of Organic Chemistry, 1984, 49(22), 4226-4237.
  • 3Paul Krapcho A. Synthetic applications of dealkoxycarbonylations of malonate esters, β-keto esters, a-cyano esters and related compounds in dipolar aproticmedia-part l[J]. Synthesis, 1982: 805-822.

同被引文献15

引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部