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Cu~Ⅰ-Gd~Ⅲ异金属二维配位聚合物[Gd~ⅢCu_2~Ⅰ(Hbpdc)_4]·Cl·8H_2O的制备及晶体结构（英文） 被引量：1

Preparation and crystal structure of a two-dimensional Cu~Ⅰ-Gd~Ⅲ heterometallic coordination polymer[Gd~ⅢCu_2~Ⅰ(Hbpdc)_4]·Cl·8H_2O
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摘要 在水热条件下合成了一例CuⅠ-GdⅢ异金属二维结构的配位聚合物[GdⅢCuⅠ2(Hbpdc)4]·Cl·8H2O(1)(H2bpdc=2,2′-联吡啶-5,5′-二羧酸),并对其结构进行了表征.X射线单晶衍射结果表明1属于单斜晶系,C2/c空间群.化合物1最显著的结构特征是Gd3+阳离子与[Cu(Hbpdc)2]-阴离子交替连接形成二维网状结构,结晶水分子有规律地填充在二维层的间隙中. A CuⅠ-GdⅢheterometallic coordination polymer[GdⅢCuⅠ2（Hbpdc）4]·Cl·8H2O（H2bpdc= 2,2′-bipyridyl-5,5′-dicarboxylic acid）（1）with a two-dimensional extended architecture has been hydrothermally obtained and structurally characterized.Single-crystal X-ray diffraction indicates that 1 belongs to the monoclinic space group C2/c.The most prominent structural characteristic of 1is that Gd3＋cations and[Cu（Hbpdc）2]- anions are distributed alternatively to form an aesthetic two-dimensional network structure with lattice water molecules stuffing in the neighboring interlayer voids regularly.
作者 赵俊伟 马杏 李兴华 刘云
机构地区 河南大学化学化工学院
出处 《化学研究》 CAS 2015年第4期373-377,共5页 Chemical Research
基金 Foundation of Education Department of Henan Province(122300410106)
关键词 异金属配位聚合物 2 2′-联吡啶-5 5′-二羧酸 水热环境 heterometallic coordination polymer 2,2＇-bipyridyl-5,5＇-dicarboxylic acid hydro-thermal environment
分类号 O614.3 [理学—无机化学]
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参考文献15

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化学研究
2015年 第4期

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